Tetrakis(triethyl phosphite)nickel(0)
作者： Gregory T. Whiteker
关键词: Aldol reaction 、 Catalysis 、 Medicinal chemistry 、 Organic chemistry 、 Isomerization 、 Alkene 、 Tsuji–Trost reaction 、 Toluene 、 Chemistry 、 Chloride 、 Nickel
摘要: [14839-39-5] C24H60NiO12P4 (MW 723.41) InChI = 1S/4C6H15O3P.Ni/c4*1-4-7-10(8-5-2)9-6-3;/h4*4-6H2,1-3H3; InChIKey = JUKYOMUOYLFUMV-UHFFFAOYSA-N (catalyst for allylic alkylation;1 cycloadditions;2 alkene isomerization;3 aldol reaction4) Physical Data: mp 108 °C; white crystals. Solubility: sol THF, toluene. Preparative Methods: easily synthesized by the reaction of Triethyl Phosphite, Nickel(II) Chloride, and Et2NH.5 Handling, Storage, Precautions: is a cancer suspect agent; air sensitive; reacts with halogenated solvents; should be handled using Schlenk or glovebox techniques.
sci-hub.se 参考文章(6)
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Max Meier, Fred Basolo, W. R. Kroll, D. Moy, M. G. Romanelli, Tetrakis(Triethyl Phosphite)Nickel(0), Palladium(0), and Platinum(0) Complexes John Wiley & Sons, Inc.. pp. 104- 107 ,(2007) , 10.1002/9780470132449.CH21