Correlation between the reactivity and the structural and thermal properties of supported metal nitrates
作者： S. Békássy , T. Cseri , G. Kenessey , G. Pokol , K. Tomor
DOI: 10.1007/BF02546892
关键词: Nitrate 、 Reactivity (chemistry) 、 Inorganic chemistry 、 Reagent 、 Copper 、 Thermal decomposition 、 Decomposition 、 Thermogravimetry 、 Hydrate 、 Chemistry
摘要: Montmorillonite-supported iron(III) nitrate and copper(II) reagents, other supported metal nitrates prepared in the same way, were investigated by thermal X-ray powder diffraction methods. The are present on support form of crystalline hydrate not as acetone solvate supposed earlier. Thermal decomposition that active model reactions proceeds a different way from practically inactive nitrates. In former case, water release itself simultaneous process. These results contributed to determination suitable reaction conditions for montmorillonite-supported reagents.
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sci-hub.se 参考文章(6)
Pierre Laszlo, Preparative chemistry using supported reagents Academic Press. ,(1987)
Keith Smith, Solid Supports and Catalysts in Organic Synthesis Ellis Horwood. ,(1992)
P. LASZLO, Chemical Reactions on Clays Science. ,vol. 235, pp. 1473- 1477 ,(1987) , 10.1126/SCIENCE.235.4795.1473
Jacob Mu, D.D. Perlmutter, Thermal decomposition of metal nitrates and their hydrates Thermochimica Acta. ,vol. 56, pp. 253- 260 ,(1982) , 10.1016/0040-6031(82)87033-0
André Cornelis, Pierre Laszlo, Clay-supported copper(II) and iron(III) nitrates: novel multi-purpose reagents for organic synthesis Synthesis. ,vol. 1985, pp. 909- 918 ,(1985) , 10.1055/S-1985-31382
L. Gubrynowicz, T. Strömich, Study on the thermal decomposition of chromium(III) nitrate nonahydrate (CNN) Thermochimica Acta. ,vol. 115, pp. 137- 151 ,(1987) , 10.1016/0040-6031(87)88360-0