Polypyrrole as possible electrode materials for the aqueous-based rechargeable zinc batteries

作者: B.N. Grgur , M.M. Gvozdenović , J. Stevanović , B.Z. Jugović , V.M. Marinović

DOI: 10.1016/J.ELECTACTA.2008.01.056

关键词: Sodium citratePolypyrroleInorganic chemistryMaterials scienceElectrochemistryChlorideElectrolyteZincAmmonium chlorideElectrode

摘要: Polypyrrole (PPy) thin film electrode was galvanostatically synthesized and characterized in 0.1 M HCl on graphite as cathode materials for the aqueous-based rechargeable zinc batteries. The charge/discharge characteristics of PPy ammonium chloride with addition sodium citrate were investigated. Electrochemical characteristic possible Zn|PPy cell chloride/citrate containing electrolyte discussed simulated.

参考文章(26)
Branimir N. Grgur, Stojan S Djokić, Konstantin I. Popov, Fundamental aspects of electrometallurgy Kluwer Academic/Plenum Publishers. ,(2002)
I. Fernández, M. Trueba, C.A. Núñez, J. Rieumont, Some features of the overoxidation of polypyrrole synthesized on austenitic stainless steel electrodes in aqueous nitrate solutions Surface & Coatings Technology. ,vol. 191, pp. 134- 139 ,(2005) , 10.1016/J.SURFCOAT.2004.03.024
Giuliano Mengoli, Marco M. Musiani, Derek Pletcher, Sergio Valcher, Studies of Zn/ZnX2/polyaniline batteries. I: X=Cl and Br Journal of Applied Electrochemistry. ,vol. 17, pp. 515- 524 ,(1987) , 10.1007/BF01084125
Lj. D. Arsov, W. Plieth, G. Koßmehl, Electrochemical and Raman spectroscopic study of polyaniline; influence of the potential on the degradation of polyaniline Journal of Solid State Electrochemistry. ,vol. 2, pp. 355- 361 ,(1998) , 10.1007/S100080050112
Khadijeh Ghanbari, Mir Fazlollah Mousavi, Mojtaba Shamsipur, Hassan Karami, Synthesis of polyaniline/graphite composite as a cathode of Zn-polyaniline rechargeable battery Journal of Power Sources. ,vol. 170, pp. 513- 519 ,(2007) , 10.1016/J.JPOWSOUR.2007.02.090
J. Wang, J. Chen, C.Y. Wang, D. Zhou, C.O. Too, G.G. Wallace, Electrochemical synthesis of polypyrrole films using stainless steel mesh as substrate for battery application Synthetic Metals. ,vol. 153, pp. 117- 120 ,(2005) , 10.1016/J.SYNTHMET.2005.07.234
Fritz Beck, Paul Rüetschi, Rechargeable batteries with aqueous electrolytes Electrochimica Acta. ,vol. 45, pp. 2467- 2482 ,(2000) , 10.1016/S0013-4686(00)00344-3
J. Wang, C.Y. Wang, C.O. Too, G.G. Wallace, Highly-flexible fibre battery incorporating polypyrrole cathode and carbon nanotubes anode Journal of Power Sources. ,vol. 161, pp. 1458- 1462 ,(2006) , 10.1016/J.JPOWSOUR.2006.05.038
A Malinauskas, J Malinauskiene, A Ramanavičius, Conducting polymer-based nanostructurized materials: electrochemical aspects. Nanotechnology. ,vol. 16, ,(2005) , 10.1088/0957-4484/16/10/R01
Huyen N. Dinh, Jianfu Ding, S.J. Xia, Viola I. Birss, Multi-technique study of the anodic degradation of polyaniline films Journal of Electroanalytical Chemistry. ,vol. 459, pp. 45- 56 ,(1998) , 10.1016/S0022-0728(98)00286-1