Iron-containing proteins and related analogs — complementary Mössbauer, EPR and magnetic susceptibility studies

作者: Alfred X. Trautwein , Eckhard Bill , Emile L. Bominaar , Heiner Winkler

DOI: 10.1007/3-540-54261-2_1

关键词: Physical chemistryElectron paramagnetic resonanceMagnetismElectronic structureInterpretation (model theory)Magnetic susceptibilityMaterials scienceMössbauer spectroscopy

摘要: The three methods covered by this review — Mossbauer spectroscopy, electron paramagnetic resonance and magnetic susceptibility-provide a powerful set of tools for detailed studies electronic structure molecular magnetism iron-containing proteins related analogs. interpretation measured data is based on the spin-Hamiltonian concept which described in detail. A short introduction to principles as well basic description spectrometers given. major part deals with applications, e.g. mononuclear iron complexes spin-coupled complexes. Wherever possible, complementarity applying described.

参考文章(150)
R N Mullinger, R Cammack, K K Rao, D O Hall, D P Dickson, C E Johnson, J D Rush, A Simopoulos, Physicochemical characterization of the four-iron-four-sulphide ferredoxin from Bacillus stearothermophilus Biochemical Journal. ,vol. 151, pp. 75- 83 ,(1975) , 10.1042/BJ1510075
Gerald M. Rothberg, Advances in Mössbauer spectroscopy Materials Science and Engineering. ,vol. 72, pp. 101- ,(1985) , 10.1016/0025-5416(85)90070-9
Gunther Louis Eichhorn, Luigi G. Marzilli, Advances in Inorganic Biochemistry ,(1994)
Eckard Münck, [20] Mössbauer spectroscopy of proteins: Electron carriers Methods in Enzymology. ,vol. 54, pp. 346- 379 ,(1978) , 10.1016/S0076-6879(78)54023-8
John Bannister Goodenough, Magnetism and the chemical bond ,(1963)
Dante Gatteschi, Alessandro Bencini, Electron Paramagnetic Resonance of Exchange Coupled Systems ,(1990)