Exciplex liquid-phase thermometer using time-resolved laser-induced fluorescence

作者: Christian Parigger , David H. Plemmons , Ron J. Litchford , San-Mou Jeng

DOI: 10.1364/OL.23.000076

关键词: Dye laserOpticsExcited stateLaser-induced fluorescencePhotoexcitationOptoelectronicsResonance fluorescenceExcimerFluorescenceExcimer laserMaterials scienceAnalytical chemistryAtomic and Molecular Physics, and Optics

摘要: Pulsed photoexcitation of hydrocarbon fuels doped with organic molecules exhibits a temperature-dependent fluorescence spectrum that is used as the basis for weakly intrusive optical thermometer. By use pulsed excitation from 308-nm 8-ns XeCl excimer laser gated detection emissions n-heptane, we demonstrate time-resolved measurement excited monomer and redshifted excited-state complex (exciplex) can yield sub-1° accuracy temperatures ranging 440??K to vicinity critical temperature (540??K).?The experiments also show exciplex pressure independent below above supercritical pressure.

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