Recent advances in developing new axially chiral phosphine ligands for asymmetric catalysis
作者： Y LI , F KWONG , W YU , A CHAN
DOI: 10.1016/J.CCR.2007.07.020
关键词: Enantioselective synthesis 、 Catalysis 、 Phosphine 、 Original research 、 Organic chemistry 、 Chemistry 、 Combinatorial chemistry 、 Steric effects
摘要: Abstract This review article illustrates the concept and approach for designing new C 2 -symmetric chelating atropisomeric chiral phosphines containing heterocyclic scaffolds. The versatility in structural modification is highlighted, that it offers an effective avenue to access ligands of diverse electronic steric properties optimization various catalytic asymmetric transformations. In this article, uses some transformations such as hydrogenation alkyl-/arylation reactions will be discussed with reference updated literature findings well author's original research.
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