A study of the thermal degradation of poly(mono-n-alkyl itaconates)
作者： José L. Velada , Carlos Cesteros , Ana Madoz , Issa Katime
DOI: 10.1002/MACP.1995.021961008
关键词: Differential scanning calorimetry 、 Polymer 、 Polymer chemistry 、 Chemistry 、 Thermogravimetry 、 Decarboxylation 、 Infrared spectroscopy 、 Fourier transform infrared spectroscopy 、 Evolved gas analysis 、 Alkyl 、 Physical and Theoretical Chemistry 、 Organic chemistry 、 Materials Chemistry 、 Polymers and Plastics 、 Condensed matter physics
摘要: The thermal degradation of the first six members poly(mono-n-alkyl itaconates) by thermogravimetry (TG), differential scanning calorimetry (DSC), Fourier Transform infrared (FTIR) and FTIR evolved gas analysis (FTIR-EGA) was studied. mechanism involves cyclic anhydride formation followed crosslinking due to linear formation. In both processes water and/or alcohol evolution detected. Also, decarboxylation take place on all polymers at high temperatures ( > 180°C). A process is proposed.
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