Fluorescence Lifetime of Benzene and Benzene‐d6 Vapor Excited to Single Vibronic Levels
作者： Benjamin K. Selinger , William R. Ware
DOI: 10.1063/1.1674464
关键词: Quenching (fluorescence) 、 Benzene 、 Atomic physics 、 Quantum yield 、 Excited state 、 Excitation 、 Isopentane 、 Kinetic isotope effect 、 Chemistry 、 Deuterium 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The fluorescence decay curves and lifetimes of benzene benzene‐d6 vapor have been determined for excitation to each several low‐lying single vibronic levels the 1B2u state. Measurements were made at pressures as low 0.1 torr, where system is essentially collision free, higher both plus an added thermalizing gas. lifetime was found vary with vibrational level acting origin emission. variation radiative consistent predictions Herzberg–Teller Theory vibronically induced transition. In addition, there appears be a deuterium isotope effect on nonradiative processes. obtained permit re‐examination some steady‐state data in literature pertaining quantum yield pressure. Also, inefficient electronic quenching when isopentane used
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sci-hub.se 参考文章(28)
Angelo A. Lamola, William R. Ware, Creation and detection of the excited state M. Dekker. ,(1971)
Isadore B. Berlman, Handbook of Fluorescence Spectra of Aromatic Molecules ,(1971)
G. W. Robinson, R. P. Frosch, Theory of Electronic Energy Relaxation in the Solid Phase The Journal of Chemical Physics. ,vol. 37, pp. 1962- 1973 ,(1962) , 10.1063/1.1733413
H. F. Kemper, M. Stockburger, Vibrational Relaxation and Its Competition with Radiationless Transitions in the 1B2u State of Benzene The Journal of Chemical Physics. ,vol. 53, pp. 268- 275 ,(1970) , 10.1063/1.1673774
M. Nishikawa, P. K. Ludwig, Fluorescence Lifetimes of Vibronic States of Benzene in the Vapor Phase The Journal of Chemical Physics. ,vol. 52, pp. 107- 112 ,(1970) , 10.1063/1.1672654
S. J. Strickler, Robert A. Berg, Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules The Journal of Chemical Physics. ,vol. 37, pp. 814- 822 ,(1962) , 10.1063/1.1733166
W. Siebrand, Radiationless Transitions in Polyatomic Molecules. I. Calculation of Franck—Condon Factors The Journal of Chemical Physics. ,vol. 46, pp. 440- 447 ,(1967) , 10.1063/1.1840685
W. F. Radle, C. A. Beck, An Experimental Study of the Near Ultraviolet Absorption Spectrum of Benzene Journal of Chemical Physics. ,vol. 8, pp. 507- 513 ,(1940) , 10.1063/1.1750702
W. Albert Noyes, W. A. Mulac, D. A. Harter, Some Aspects of the Photochemistry of Benzene Journal of Chemical Physics. ,vol. 44, pp. 2100- 2106 ,(1966) , 10.1063/1.1726987
W. Albert Noyes, D. A. Harter, Vibrational Effects in the Xylenes Journal of the American Chemical Society. ,vol. 91, pp. 7585- 7589 ,(1969) , 10.1021/JA50001A009