A facile strategy to recycle template P123 from mesoporous aluminosilicates by ultrasonic extraction

作者: Jun-su Jin , Li Cao , Guang-xun Su , Chun-yan Xu , Ze-ting Zhang

DOI: 10.1016/J.ULTSONCH.2014.02.025

关键词: Mesoporous materialSonicationExtraction (chemistry)Materials scienceChemical engineeringCalcinationCopolymerAluminosilicateUltrasonic sensorAcoustics and UltrasonicsChemical Engineering (miscellaneous)Radiology Nuclear Medicine and imaging

摘要: High synthesis cost of mesoporous aluminosilicates (MA) limits their practical application. Recycling copolymer template employed in preparation MA is an effective way to reduce the cost. An ultrasonic extraction strategy for recycling organic P123 MAs reported. Effects different parameters on recovery are investigated and optimum conditions obtained. 75.0% recovered from within 10 min by one-step ultrasonication. Characterizations indicated that resulting P123-free (MA-U) exhibits excellent properties compared with calcined products. Moreover, can be synthesize high hydrothermally stable MA. This investigation provides a facile recycle

参考文章(47)
C. KOZMUTZA, E. TFIRST, F. BARTHA, O. KAPUY, STUDY OF INTERACTION ABILITIES USING AN ENERGY PARTITIONING SCHEME IN SOME WATER CLUSTERS Springer, Dordrecht. pp. 337- 345 ,(2006) , 10.1007/1-4020-4528-X_16
Bozhi Tian, Xiaoying Liu, Chengzhong Yu, Feng Gao, Qian Luo, Songhai Xie, Bo Tu, Dongyuan Zhao, Microwave assisted template removal of siliceous porous materials Chemical Communications. ,vol. 11, pp. 1186- 1187 ,(2002) , 10.1039/B202180C
Qingfeng Tan, Yu Fan, Haiyan Liu, Tengchun Song, Gang Shi, Baojian Shen, Xiaojun Bao, Bimodal micro‐mesoporous aluminosilicates for heavy oil cracking: Porosity tuning and catalytic properties Aiche Journal. ,vol. 54, pp. 1850- 1859 ,(2008) , 10.1002/AIC.11512
Hua Ji, Yiqun Fan, Wanqin Jin, Changlin Chen, Nanping Xu, Synthesis of Si-MCM-48 membrane by solvent extraction of the surfactant template Journal of Non-crystalline Solids. ,vol. 354, pp. 2010- 2016 ,(2008) , 10.1016/J.JNONCRYSOL.2007.11.011
Huaqiang Cai, Dongyuan Zhao, A mild method to remove organic templates in periodic mesoporous organosilicas by the oxidation of perchlorates Microporous and Mesoporous Materials. ,vol. 118, pp. 513- 517 ,(2009) , 10.1016/J.MICROMESO.2008.08.049
F. Bérubé, S. Kaliaguine, Calcination and thermal degradation mechanisms of triblock copolymer template in SBA-15 materials Microporous and Mesoporous Materials. ,vol. 115, pp. 469- 479 ,(2008) , 10.1016/J.MICROMESO.2008.02.028
Dongyuan Zhao, Qisheng Huo, Jianglin Feng, Bradley F. Chmelka, Galen D. Stucky, Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures Journal of the American Chemical Society. ,vol. 120, pp. 6024- 6036 ,(1998) , 10.1021/JA974025I
Enrique Riera, Alfonso Blanco, José García, José Benedito, Antonio Mulet, Juan A. Gallego-Juárez, Miguel Blasco, High-power ultrasonic system for the enhancement of mass transfer in supercritical CO2 extraction processes Ultrasonics. ,vol. 50, pp. 306- 309 ,(2010) , 10.1016/J.ULTRAS.2009.09.015
Rafael Van Grieken, Guillermo Calleja, Galen D Stucky, Juan A Melero, Rafael A García, Jose Iglesias, None, Supercritical Fluid Extraction of a Nonionic Surfactant Template from SBA-15 Materials and Consequences on the Porous Structure Langmuir. ,vol. 19, pp. 3966- 3973 ,(2003) , 10.1021/LA026970C
Zhen Huang, Li Xu, Jing-Huan Li, S. Kawi, A.H. Goh, Organic template removal from hexagonal mesoporous silica by means of methanol-enhanced CO2 extraction: Effect of temperature, pressure and flow rate Separation and Purification Technology. ,vol. 77, pp. 112- 119 ,(2011) , 10.1016/J.SEPPUR.2010.11.029