Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

摘要: Single crystal X-ray analysis at 100 K reveals that in the trigonal CCl4quasiracemic clathrate, space group R3, formed from host components S-(−)-Dianin's compound and its (+)-2R,4R 2-nor methyl analogue there is an unprecedented complete ordering of a C–Cl bond guest with respect to c-axial direction. In this clathrate (+)-2R,4S epimers participation unexpected conformation reported for first time.