Synthesis, properties and reactivity of mononuclear Rh(I) and Ir(I) complexes of s- and as-hydroindacenide ligands
作者： Annalisa Bisello , Alberto Ceccon , Alessandro Gambaro , Paolo Ganis , Francesco Manoli
DOI: 10.1016/S0022-328X(99)00522-7
关键词: Deprotonation 、 Salt (chemistry) 、 Stereochemistry 、 Reactivity (chemistry) 、 Medicinal chemistry 、 Chemistry 、 Bridging ligand 、 Ion pairs
摘要: The monometallic complexes with Rh(COD) and Ir(COD) of 1,5- 1,7-dihydro- s -indacene, 2,6-dimethyl-1,5-dihydro- -indacene 2,7-dimethyl-1,6-dihydro- as have been synthesized characterized spectroscopically structurally. Deprotonation further complexation these compounds afforded mixtures syn anti homobimetallic isomers. / ratio depends on the structure ion pairs salt or geometry bridging ligand.
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