New fluorescent monomers and polymers displaying an intramolecular proton-transfer mechanism in the electronically excited state. III. Thermogravimetric stability study of the benzazolylvinylene derivatives
作者： Leandra Franciscato Campo , Fabiano Severo Rodembusch , Valter Stefani
DOI: 10.1002/APP.22292
关键词: Thermal stability 、 Atmospheric temperature range 、 Physical chemistry 、 Excited state 、 Chemistry 、 Thermogravimetric analysis 、 Order of reaction 、 Polymer chemistry 、 Differential scanning calorimetry 、 Activation energy 、 Polymer
摘要: Six fluorescent benzazolylvinylene derivatives were studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and related molecular parameters. The thermal stability was determined in terms of the steps degradation its fitting parameters, such as maximum rate (Rmax), temperature (TRmax), range, which is to half-width at half-height values (Γ), kinetic parameters: activation energy (Ea), pre-exponential factor (A), reaction order (n) obtained Barrett's method. Different organic substitutes heteroatoms do not play a fundamental role behavior dyes. compensation effect between confirmed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 495–500, 2006
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