The pyrolysis of duckweed over a solid base catalyst: Py-GC/MS and TGA analysis

作者: Changyan Yang , Rui Li , Chang Cui , Jinsheng Wu , Yigang Ding

DOI: 10.1080/15567036.2016.1214641

关键词: EthylbenzenePyrolysisGas chromatography–mass spectrometryCatalysisThermogravimetric analysisAlkyl substitutionChemistryOrganic chemistryLemna minorSolid base

摘要: ABSTRACTThe possibility of using the solid base as pyrolysis catalyst to synthesize chemicals from duckweed (Lemna minor) was explored. Thermogravimetric analyses indicated that conversion in slow approximately 60 wt%. Direct could form various hydrocarbons and precursors for industrious products. When pyrolyzing this species with catalyst, new such 3-methyl-butanal, cyclobutanol, 2-methyl-1H-pyrrole, ethylbenzene, 2-pyrrolidinone, 4-ethyl-phenol were synthesized. The results application mainly enhanced alkyl substitution reactions direct complex preferred

参考文章(15)
Yiqin Wan, Hanwu Lei, Paul Chen, Roger Ruan, Xiangyang Lin, Bo Zhang, Kevin Hennessy, Johannes Moen, Changyan Yang, Yuhuan Liu, Fractionation and characterization of bio-oil from microwave-assisted pyrolysis of corn stover International Journal of Agricultural and Biological Engineering. ,vol. 3, pp. 54- 61 ,(2010) , 10.3965/J.ISSN.1934-6344.2010.03.054-061
John Coates, Interpretation of Infrared Spectra, A Practical Approach Encyclopedia of Analytical Chemistry. ,(2006) , 10.1002/9780470027318.A5606
Xumeng Ge, Ningning Zhang, Gregory C. Phillips, Jianfeng Xu, Growing Lemna minor in agricultural wastewater and converting the duckweed biomass to ethanol. Bioresource Technology. ,vol. 124, pp. 485- 488 ,(2012) , 10.1016/J.BIORTECH.2012.08.050
Yiqin Wan, Paul Chen, Bo Zhang, Changyang Yang, Yuhuan Liu, Xiangyang Lin, Roger Ruan, Microwave-assisted pyrolysis of biomass: Catalysts to improve product selectivity Journal of Analytical and Applied Pyrolysis. ,vol. 86, pp. 161- 167 ,(2009) , 10.1016/J.JAAP.2009.05.006
Liu GuangYi Liu GuangYi, MM Wright, Zhao QingLiang Zhao QingLiang, RC Brown, Catalytic fast pyrolysis of duckweed: effects of pyrolysis parameters and optimization of aromatic production. Journal of Analytical and Applied Pyrolysis. ,vol. 112, pp. 29- 36 ,(2015) , 10.1016/J.JAAP.2015.02.026
B. Zhang, C. Yang, J. Moen, Z. Le, K. Hennessy, Y. Wan, Y. Liu, H. Lei, P. Chen, R. Ruan, Catalytic Conversion of Microwave-assisted Pyrolysis Vapors Energy Sources Part A-recovery Utilization and Environmental Effects. ,vol. 32, pp. 1756- 1762 ,(2010) , 10.1080/15567030902842285
Peigao Duan, Zhoufan Chang, Yuping Xu, Xiujun Bai, Feng Wang, Lei Zhang, Hydrothermal processing of duckweed: effect of reaction conditions on product distribution and composition. Bioresource Technology. ,vol. 135, pp. 710- 719 ,(2013) , 10.1016/J.BIORTECH.2012.08.106
Mo Xian, None, Recent Development of Bioenergy and Biorefinery in China Trends in Renewable Energy. ,vol. 1, pp. 129- 130 ,(2015) , 10.17737/TRE.2015.1.3.0015