An assessment of the technique of simultaneous cooling in conjunction with microwave heating for organic synthesis
作者： Nicholas E. Leadbeater , Sharon J. Pillsbury , Erik Shanahan , Victoria A. Williams
DOI: 10.1016/J.TET.2005.01.105
关键词: Photochemistry 、 Microwave 、 Chemistry 、 Microwave heating 、 Heck reaction 、 Michael reaction 、 Diels–Alder reaction 、 Cycloaddition 、 Organic synthesis 、 Temperature measurement
摘要: Abstract In the light of controversy in area and since reports using simultaneous cooling conjunction with microwave heating are appearing literature, we were keen to assess methodology, looking at temperature measurement issues as well use technique three classes reaction, namely a Heck coupling, Diels–Alder cycloaddition Michael addition. We present our initial findings here.
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R.M. Martín-Aranda, E. Ortega-Cantero, M.L. Rojas-Cervantes, M.A. Vicente-Rodríguez, M.A. Bañares-Muñoz, Sonocatalysis and Basic Clays. Michael Addition Between Imidazole and Ethyl Acrylate Catalysis Letters. ,vol. 84, pp. 201- 204 ,(2002) , 10.1023/A:1021480020425
Karine Guillou, Jack Hamelin, Ludovic Paquin, Françoise Texier-Boullet, Loı̈c Toupet, Olivier Correc, Microwave solvent-free synthesis of nitrocyclohexanols Tetrahedron Letters. ,vol. 45, pp. 391- 395 ,(2004) , 10.1016/J.TETLET.2003.10.148
Irina P. Beletskaya, Andrei V. Cheprakov, The Heck Reaction as a Sharpening Stone of Palladium Catalysis Chemical Reviews. ,vol. 100, pp. 3009- 3066 ,(2000) , 10.1021/CR9903048
Varinder K. Aggarwal, J. Robin Fulton, Chris G. Sheldon, Javier de Vicente, Generation of phosphoranes derived from phosphites. A new class of phosphorus ylides leading to high E selectivity with semi-stabilizing groups in Wittig olefinations. Journal of the American Chemical Society. ,vol. 125, pp. 6034- 6035 ,(2003) , 10.1021/JA029573X
Laurence Perreux, André Loupy, A tentative rationalization of microwave effects in organic synthesis according to the reaction medium, and mechanistic considerations Tetrahedron. ,vol. 57, pp. 9199- 9223 ,(2001) , 10.1016/S0040-4020(01)00905-X
J. Berlan, P. Giboreau, S. Lefeuvre, C. Marchand, Synthese organique sous champ microondes : premier exemple d'activation specifique en phase homogene Tetrahedron Letters. ,vol. 32, pp. 2363- 2366 ,(1991) , 10.1016/S0040-4039(00)79924-2
Mats Larhed, Anders Hallberg, Microwave-Promoted Palladium-Catalyzed Coupling Reactions Journal of Organic Chemistry. ,vol. 61, pp. 9582- 9584 ,(1996) , 10.1021/JO9612990
N.A. Bumagin, P.G. More, I.P. Beletskaya, Synthesis of substituted cinnamic acids and cinnamonitriles via palladium catalyzed coupling reactions of aryl halides with acrylic acid and acrylonitrile in aqueous media Journal of Organometallic Chemistry. ,vol. 371, pp. 397- 401 ,(1989) , 10.1016/0022-328X(89)85235-0
Didier Villemin, Fredéric Caillot, Microwave mediated palladium-catalysed reactions on potassium fluoride/alumina without use of solvent Tetrahedron Letters. ,vol. 42, pp. 639- 642 ,(2001) , 10.1016/S0040-4039(00)02027-X
Amy Lew, Peter O. Krutzik, Matthew E. Hart, A. Richard Chamberlin, Increasing rates of reaction: microwave-assisted organic synthesis for combinatorial chemistry. ACS Combinatorial Science. ,vol. 4, pp. 95- 105 ,(2002) , 10.1021/CC010048O