Role of Small Clusters in Nucleation about Ions

作者: A. W. Castleman , I. N. Tang

DOI: 10.1063/1.1678819

关键词: Atomic physicsNucleationChemical physicsChemistryIonSolvationCluster (physics)

摘要: A consideration of the molecular aspects ion induced nucleation shows that, in contrast to accepted theory, small clusters are a segment over‐all size spectrum. No direct relationship exists between solvation energy and free barrier for nucleation. Instead, it is established that properties govern functions neighborhood peak cluster concentration, these turn affect height The fact ion‐molecule reactions taking place during course usual experiment clearly demonstrated. Assumptions generally occurs directly about ions carrier gas disproven.

参考文章(30)
Jonathan Frankel, Kinetic theory of liquids Clarendon Press. ,(1946)
I. N. Tang, A. W. Castleman, Mass Spectrometric Study of the Gas‐Phase Hydration of the Monovalent Lead Ion The Journal of Chemical Physics. ,vol. 57, pp. 3638- 3644 ,(1972) , 10.1063/1.1678820
Condensation phenomena at different temperatures Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 119, pp. 553- 577 ,(1928) , 10.1098/RSPA.1928.0114
G. M. Pound, Selected Values of Critical Supersaturation for Nucleation of Liquids from the Vapor Journal of Physical and Chemical Reference Data. ,vol. 1, pp. 119- 133 ,(1972) , 10.1063/1.3253095
C. S. Kiang, D. Stauffer, G. H. Walker, O. P. Puri, J. D. Wise, E. M. Patterson, A Reexamination of Homogeneous Nucleation Theory Journal of the Atmospheric Sciences. ,vol. 28, pp. 1222- 1232 ,(1971) , 10.1175/1520-0469(1971)028<1222:AROHNT>2.0.CO;2
D.R. White, J.L. Kassner, Experimental and theoretical study of the sign preference in the nucleation of water vapor Journal of Aerosol Science. ,vol. 2, pp. 201- 206 ,(1971) , 10.1016/0021-8502(71)90028-0
Hans Dolezalek, The atmospheric electric fog effect Reviews of Geophysics. ,vol. 1, pp. 231- 282 ,(1963) , 10.1029/RG001I002P00231
Louis B Allen, James L Kassner, The nucleation of water vapor in the absence of particulate matter and ions Journal of Colloid and Interface Science. ,vol. 30, pp. 81- 93 ,(1969) , 10.1016/0021-9797(69)90381-6
B. J. Mason, F. H. Ludlam, The physics of clouds ,(1971)