Polymer/carbon nanotube nanocomposites via noncovalent grafting with end‐functionalized polymers

作者: Sun Hwa Lee , Ji Sun Park , Bo Kyung Lim , Sang Ouk Kim

DOI: 10.1002/APP.27920

关键词: Hydrogen bondPolymer chemistryMaterials scienceSurface modificationPolymerNanocompositeCarbon nanotubeEnd-groupCarboxylic acidPolystyrene

摘要: Polymer/carbon nanotube nanocomposites were fabricated with end-functionalized polymers as dis- persants. End-functionalized having amine or carboxylic acid noncovalently grafted to multiwalled nanotubes (MWNTs). The functional groups of the poly- mers interacted defect sites purified MWNTs through zwitterionic interactions hydrogen bonding. This approach provided both an improved dispersion state in organic solution and polymer matrix good interfacial adhesion between a matrix. Physical properties, such electrical resistivity mechanical strength, polystyrene/MWNT nanocompo- greatly this simple noncova- lent functionalization. 2008 Wiley Periodicals, Inc. J Appl Polym Sci 110: 2345-2351,

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