A study on the crystallization behaviour of polypropylene, polyethylene and their blends by dynamic mechanical and thermal methods
作者： J.W. Teh , H.P. Blom , A. Rudin
DOI: 10.1016/0032-3861(94)90842-7
关键词: Differential scanning calorimetry 、 Polyethylene 、 Avrami equation 、 Nucleation 、 Optical microscope 、 Crystallization 、 Crystallization of polymers 、 Polymer chemistry 、 Polypropylene 、 Materials science 、 Composite material
摘要: Abstract Studies on the crystallization of polymers are usually carried out by dilatometry, differential scanning calorimetry (d.s.c.) and optical microscopy. These methods have been widely used in analysis kinetics using Avrami equation. Direct determination nucleation rate density is only possible microscope technique. We employed a new technique for studying behaviour dynamic mechanical method. This method capable detecting onset nucleation. Semiquantitative data initial may also be deduced this Results from cross-compared with d.s.c. polypropylene, polyethylene their blends, shown to mutually consistent.
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sci-hub.se 参考文章(14)
Allan Sharples, Introduction to polymer crystallization ,(1966)
Robert F. Landel, Lawrence E. Nielsen, Mechanical Properties of Polymers and Composites ,(1993)
J. W. Teh, A. Rudin, Properties and morphology of polystyrene and linear low density polyethylene polyblend and polyalloy Polymer Engineering and Science. ,vol. 31, pp. 1033- 1042 ,(1991) , 10.1002/PEN.760311407
Oscar F. Noel, James F. Carley, Properties of polypropylene-polyethylene blends Polymer Engineering and Science. ,vol. 15, pp. 117- 126 ,(1975) , 10.1002/PEN.760150212
Lawrence E. Nielsen, Generalized Equation for the Elastic Moduli of Composite Materials Journal of Applied Physics. ,vol. 41, pp. 4626- 4627 ,(1970) , 10.1063/1.1658506
David K. Potter, Alfred Rudin, Entanglement spacing variability in polystyrenes with narrow molecular weight distributions Macromolecules. ,vol. 24, pp. 213- 224 ,(1991) , 10.1021/MA00001A034
Z. Bartczak, A. Galeski, M. Pracella, Spherulite nucleation in blends of isotactic polypropylene with high-density polyethylene Polymer. ,vol. 27, pp. 537- 543 ,(1986) , 10.1016/0032-3861(86)90239-9
Leo Mandelkern, Crystallization of polymers ,(2002)
Andrew J. Lovinger, M. L. Williams, Tensile properties and morphology of blends of polyethylene and polypropylene Journal of Applied Polymer Science. ,vol. 25, pp. 1703- 1713 ,(1980) , 10.1002/APP.1980.070250817
Ezio Martuscelli, Mariano Pracella, Gaetano Della Volpe, Pietro Greco, Morphology, crystallization, and thermal behaviour of isotactic polypropylene/low density polyethylene blends Macromolecular Chemistry and Physics. ,vol. 185, pp. 1041- 1061 ,(1984) , 10.1002/MACP.1984.021850516