Thermodynamics and kinetics of the thermal decomposition of cupric chloride in its hydrolysis reaction
作者： Z. Wang , G. Marin , G. F. Naterer , K. S. Gabriel
DOI: 10.1007/S10973-014-3929-6
关键词: Inorganic chemistry 、 Copper chloride 、 Differential scanning calorimetry 、 Thermogravimetric analysis 、 Thermal decomposition 、 Chemical decomposition 、 Chloride 、 Chemistry 、 Decomposition 、 Melting point
摘要: The hydrolysis of copper(II) chloride is the water splitting process in copper–chlorine thermochemical hydrogen production cycle. In this paper, a simultaneous differential scanning calorimetry and thermogravimetric analysis (DSC/TG) technique used to determine transitional temperature kinetics thermal decomposition CuCl2. Thermodynamic performed on reaction for comparison with results. CuCl2 obtained from experiments found be higher than that predicted thermodynamic analysis. This broadens available operating range step Cu–Cl It also product CuCl may completely evaporate if its melting point, so should operated below point (430 °C) avoid undesirable Cl2 byproducts. A preliminary correlation proposed paper terms extent converting Cl2.
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