AMINE MODIFIED MESOSTRUCTURED SILICA NANO PARTICLES ENHANCED ADSORPTION OF PHENOL

作者: NFM Salleh , AA Jalil , S Triwahyono , SN Nordin , NHN Kamarudin

DOI: 10.11113/JT.V75.5156

关键词: AdsorptionInorganic chemistryNuclear chemistrySurface modificationAmine gas treatingTriethoxysilaneMesoporous silicaCrystallinityCationic polymerizationMaterials sciencePhenol

摘要: Mesoporous silica nanoparticles (MSN) were synthesized and modified with (3-aminopropyl) triethoxysilane (APTES) using co-condensation (co-MSN) post-grafting (post-MSN) methods. Both modification methods seem to alter the crystallinity, surface area, pore volume as compared unmodified MSN. The activity of all MSNs was tested for adsorptive removal phenol. Co-MSN showed significantly good adsorptivity towards 10 mg L -1 phenols, followed by post-MSN It found that highest co-MSN resulted from additional higher adsorption energy quaternary alkylammonium groups (Si–C–C–C–[N + –(CH 3 ) ]) cationic template also amine group APTES functionalization, which more advantages

参考文章(35)
Gholamreza Moussavi, Maryam Mahmoudi, Behnam Barikbin, Biological removal of phenol from strong wastewaters using a novel MSBR. Water Research. ,vol. 43, pp. 1295- 1302 ,(2009) , 10.1016/J.WATRES.2008.12.026
J.L. Gómez, A. Bódalo, E. Gómez, J. Bastida, A.M. Hidalgo, M. Gómez, Immobilization of peroxidases on glass beads: An improved alternative for phenol removal Enzyme and Microbial Technology. ,vol. 39, pp. 1016- 1022 ,(2006) , 10.1016/J.ENZMICTEC.2006.02.008
Freddy Kleitz, Wolfgang Schmidt, Ferdi Schüth, Evolution of mesoporous materials during the calcination process: structural and chemical behavior Microporous and Mesoporous Materials. ,vol. 44-45, pp. 95- 109 ,(2001) , 10.1016/S1387-1811(01)00173-1
Somnath Mukherjee Somnath Mukherjee, Sunil Kumar Sunil Kumar, AK Misra, MH Fan, Removal of phenols from water environment by activated carbon, bagasse ash and wood charcoal Chemical Engineering Journal. ,vol. 129, pp. 133- 142 ,(2007) , 10.1016/J.CEJ.2006.10.030
Gülay Bayramoğlu, M. Yakup Arıca, Enzymatic removal of phenol and p-chlorophenol in enzyme reactor: horseradish peroxidase immobilized on magnetic beads. Journal of Hazardous Materials. ,vol. 156, pp. 148- 155 ,(2008) , 10.1016/J.JHAZMAT.2007.12.008
Jianhua Huang, Xingguo Wang, Qingzhe Jin, Yuanfa Liu, Ying Wang, Removal of phenol from aqueous solution by adsorption onto OTMAC-modified attapulgite. Journal of Environmental Management. ,vol. 84, pp. 229- 236 ,(2007) , 10.1016/J.JENVMAN.2006.05.007
Ling Huang, Qinglin Huang, Huining Xiao, Mladen Eić, Effect of cationic template on the adsorption of aromatic compounds in MCM-41 Microporous and Mesoporous Materials. ,vol. 98, pp. 330- 338 ,(2007) , 10.1016/J.MICROMESO.2006.09.032
Brian P Kelleher, Aidan M Doyle, Thomas F O'Dwyer, Benjamin K Hodnett, Preparation and use of a mesoporous silicate material for the removal of tetramethyl ammonium hydroxide (TMAH) from aqueous solution Journal of Chemical Technology & Biotechnology. ,vol. 76, pp. 1216- 1222 ,(2001) , 10.1002/JCTB.508
José Aguado, Jesús M. Arsuaga, Amaya Arencibia, Montaña Lindo, Victoria Gascón, Aqueous heavy metals removal by adsorption on amine-functionalized mesoporous silica. Journal of Hazardous Materials. ,vol. 163, pp. 213- 221 ,(2009) , 10.1016/J.JHAZMAT.2008.06.080
Yu Zhou, Yu Fei Tao, Jing Yang, Wei Gang Lin, Mi Mi Wan, Ying Wang, Jian Hua Zhu, Novel phenol capturer derived from the as-synthesized MCM-41. Journal of Hazardous Materials. ,vol. 190, pp. 87- 93 ,(2011) , 10.1016/J.JHAZMAT.2011.02.089