Highly efficient, water-soluble polarizing agents for dynamic nuclear polarization at high frequency.
作者： Claire Sauvée , Melanie Rosay , Gilles Casano , Fabien Aussenac , Ralph T. Weber
关键词: Cross effect 、 Nuclear magnetic resonance spectroscopy 、 Water soluble 、 Chemistry 、 Analytical chemistry 、 Glycerol 、 Polarization (waves)
摘要: Well polarized: Two new polarizing agents PyPol and AMUPol soluble in glycerol/water mixtures are used for dynamic nuclear polarization (DNP) NMR spectroscopy. The enhancement factors (e) about 3.5 to 4 times larger than the established agent TOTAPOL at 263 395 GHz. For AMUPol, temperature dependence of e allows DNP experiments be performed temperatures significantly higher typical high-field experiments.
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sci-hub.se 参考文章(50)
Pascal Miéville, Veronika Vitzthum, Marc A. Caporini, Sami Jannin, Sandrine Gerber-Lemaire, Geoffrey Bodenhausen, A spinning thermometer to monitor microwave heating and glass transitions in dynamic nuclear polarization Magnetic Resonance in Chemistry. ,vol. 49, pp. 689- 692 ,(2011) , 10.1002/MRC.2811
Anne Lesage, Moreno Lelli, David Gajan, Marc A. Caporini, Veronika Vitzthum, Pascal Miéville, Johan Alauzun, Arthur Roussey, Chloé Thieuleux, Ahmad Mehdi, Geoffrey Bodenhausen, Christophe Coperet, Lyndon Emsley, Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization Journal of the American Chemical Society. ,vol. 132, pp. 15459- 15461 ,(2010) , 10.1021/JA104771Z
Evgeniy Salnikov, Melanie Rosay, Shane Pawsey, Olivier Ouari, Paul Tordo, Burkhard Bechinger, Solid-state NMR spectroscopy of oriented membrane polypeptides at 100 K with signal enhancement by dynamic nuclear polarization. Journal of the American Chemical Society. ,vol. 132, pp. 5940- 5941 ,(2010) , 10.1021/JA1007646
Eric L. Dane, Björn Corzilius, Egon Rizzato, Pierre Stocker, Thorsten Maly, Albert A. Smith, Robert G. Griffin, Olivier Ouari, Paul Tordo, Timothy M. Swager, Rigid Orthogonal bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization Journal of Organic Chemistry. ,vol. 77, pp. 1789- 1797 ,(2012) , 10.1021/JO202349J
Albert W. Overhauser, Polarization of Nuclei in Metals Physical Review. ,vol. 92, pp. 411- 415 ,(1953) , 10.1103/PHYSREV.92.411
Moreno Lelli, David Gajan, Anne Lesage, Marc A Caporini, Veronika Vitzthum, Pascal Miéville, Florent Héroguel, Fernando Rascón, Arthur Roussey, Chloé Thieuleux, Malika Boualleg, Laurent Veyre, Geoffrey Bodenhausen, Christophe Copéret, Lyndon Emsley, None, Fast Characterization of Functionalized Silica Materials by Silicon-29 Surface-Enhanced NMR Spectroscopy Using Dynamic Nuclear Polarization Journal of the American Chemical Society. ,vol. 133, pp. 2104- 2107 ,(2011) , 10.1021/JA110791D
Enrico Ravera, Björn Corzilius, Vladimir K. Michaelis, Camilla Rosa, Robert G. Griffin, Claudio Luchinat, Ivano Bertini, Dynamic nuclear polarization of sedimented solutes. Journal of the American Chemical Society. ,vol. 135, pp. 1641- 1644 ,(2013) , 10.1021/JA312553B
Kan-Nian Hu, Changsik Song, Hsiao-hua Yu, Timothy M. Swager, Robert G. Griffin, High-frequency dynamic nuclear polarization using biradicals: A multifrequency EPR lineshape analysis Journal of Chemical Physics. ,vol. 128, pp. 052302- 052302 ,(2008) , 10.1063/1.2816783
Marvin J. Bayro, Galia T. Debelouchina, Matthew T. Eddy, Neil R. Birkett, Catherine E. MacPhee, Melanie Rosay, Werner E. Maas, Christopher M. Dobson, Robert G. Griffin, Intermolecular structure determination of amyloid fibrils with magic-angle spinning and dynamic nuclear polarization NMR. Journal of the American Chemical Society. ,vol. 133, pp. 13967- 13974 ,(2011) , 10.1021/JA203756X
Thomas R. Carver, Charles P. Slichter, Experimental Verification of the Overhauser Nuclear Polarization Effect Physical Review. ,vol. 102, pp. 975- 980 ,(1956) , 10.1103/PHYSREV.102.975