Synthesis and characterization of tetraalkylammonium thiomolybdates and thiotungstates in aqueous solution
作者： G Alonso , G Aguirre , IA Rivero , S Fuentes
DOI: 10.1016/S0020-1693(01)00367-X
关键词: Fourier transform 、 Chemistry 、 Aqueous solution 、 Improved method 、 Characterization (materials science) 、 Inorganic chemistry
摘要: An improved method for the preparation of (R4N)2MS4 (R = Me, Bu and M Mo, W) is reported. The rapid substitution (NH4)+ salts to [(Me)4N]+ [(Bu)4N]+ salts, via reaction with aqueous (Me)4NCl (Bu)4NBr described. Thiometallates characterization by Fourier transform IR, UV NMR spectroscopies
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H.W WANG, P SKELDON, G.E THOMPSON, G.C WOOD, Synthesis and characterization of molybdenum disulphide formed from ammonium tetrathiomolybdate Journal of Materials Science. ,vol. 32, pp. 497- 502 ,(1997) , 10.1023/A:1018538424373
G. Alonso, M. Del Valle, J. Cruz, A. Licea‐Claverie, V. Petranovskii, S. Fuentes, Preparation of MoS2 and WS2 catalysts by in situ decomposition of ammonium thiosalts Catalysis Letters. ,vol. 52, pp. 55- 61 ,(1998) , 10.1023/A:1019067319305
Michael P. Coughlan, Molybdenum and Molybdenum-Containing Enzymes ,(1979)
S Fuentes, G Diaz, F Pedraza, H Rojas, N Rosas, The influence of a new preparation method on the catalytic properties of CoMo and NiMo sulfides Journal of Catalysis. ,vol. 113, pp. 535- 539 ,(1988) , 10.1016/0021-9517(88)90280-1
G Alonso, M Del Valle, J Cruz, V Petranovskii, A Licea-Claverie, S Fuentes, Preparation of MoS2 catalysts by in situ decomposition of tetraalkylammonium thiomolybdates Catalysis Today. ,vol. 43, pp. 117- 122 ,(1998) , 10.1016/S0920-5861(98)00140-0
Thomas R. Halbert, Steven A. Cohen, Edward I. Stiefel, Construction of heterometallic "thiocubanes" from M2S2(.mu.-S)2 core complexes: synthesis of Co2M2S4(S2CNEt2)2(CH3CN)2(CO)2 (M = Mo, W) and structure of the Co2Mo2(.mu.3-S)4 cluster Organometallics. ,vol. 4, pp. 1689- 1690 ,(1985) , 10.1021/OM00128A039
Achim Müller, Ekkehard Diemann, Hans-Henning Heinsen, Übergangsmetallchalkogenverbindungen Thio-Anionen als zweizähnige Liganden in Übergangsmetall-komplexen: Darstellung und Eigenschaften von Tetrathio-wolframato-Verbindungen von NiII, CoII und ZnII Chemische Berichte. ,vol. 104, pp. 975- 980 ,(1971) , 10.1002/CBER.19711040402
K RAMANATHAN, Characterization of tungsten sulfide catalysts Journal of Catalysis. ,vol. 95, pp. 249- 259 ,(1985) , 10.1016/0021-9517(85)90025-9
M. Lacroix, N. Boutarfa, C. Guillard, M. Vrinat, M. Breysse, Hydrogenating properties of unsupported transition metal sulphides Journal of Catalysis. ,vol. 120, pp. 473- 477 ,(1989) , 10.1016/0021-9517(89)90287-X
F. Zhang, P.T. Vasudevan, TPD and HYD studies of unpromoted and co-promoted molybdenum sulfide catalyst ex ammonium tetrathiomolybdate Journal of Catalysis. ,vol. 157, pp. 536- 544 ,(1995) , 10.1006/JCAT.1995.1317