Thermodynamic analysis on energy densities of batteries

作者: Chen-Xi Zu , Hong Li

DOI: 10.1039/C0EE00777C

关键词: Chemical energyEnergy storageElectrode materialChemistryBattery (electricity)Inorganic chemistryEnergy densityNuclear engineeringEnergy (signal processing)Electrochemical energy conversion

摘要: The average increase in the rate of the energy density of secondary batteries has been about 3% in the past 60 years. Obviously, a great breakthrough is needed in order to increase the energy density from the current 210 Wh kg− 1 of Li-ion batteries to the ambitious target of 500–700 Wh kg− 1 to satisfy application in electrical vehicles. A thermodynamic calculation on the theoretical energy densities of 1172 systems is performed and energy storage mechanisms are discussed, aiming to determine the theoretical and …

参考文章(71)
C.M. Julien, Lithium intercalated compounds: Charge transfer and related properties Materials Science & Engineering R-reports. ,vol. 40, pp. 47- 102 ,(2003) , 10.1016/S0927-796X(02)00104-3
Zhenzhen Feng, Jun Yang, Yanna NuLi, Jiulin Wang, Xiaojian Wang, Zhaoxiang Wang, Preparation and electrochemical study of a new magnesium intercalation material Mg1.03Mn0.97SiO4 Electrochemistry Communications. ,vol. 10, pp. 1291- 1294 ,(2008) , 10.1016/J.ELECOM.2008.06.021
N. Pereira, L. C. Klein, G. G. Amatucci, The Electrochemistry of Zn3 N 2 and LiZnN A Lithium Reaction Mechanism for Metal Nitride Electrodes Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1446079
Christopher Blauth, Data, data, data... International Journal of Clinical Practice. ,vol. 61, pp. 1074- 1074 ,(2007) , 10.1111/J.1742-1241.2007.01405.X
A. K. Shukla, S. K. Martha, Electrochemical power sources Resonance. ,vol. 6, pp. 52- 63 ,(2001) , 10.1007/BF02835270
Ying Wang, Zheng-Wen Fu, Xiao-Li Yue, Qi-Zong Qin, Electrochemical Reactivity Mechanism of Ni3 N with Lithium Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1649983
P. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J-M. Tarascon, Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Nature. ,vol. 407, pp. 496- 499 ,(2000) , 10.1038/35035045
D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, H. Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich, E. Levi, Prototype systems for rechargeable magnesium batteries Nature. ,vol. 407, pp. 724- 727 ,(2000) , 10.1038/35037553