On the Use of Aromaticity Rules, Frontier Orbitals and Correlations Diagrams. Some Difficulties and Unsolved Problems

作者: Nguyen Trong Anh

DOI: 10.1007/978-94-009-9516-1_8

关键词: Atomic orbitalDiagramSymmetry elementAromaticityStereochemistryTheoretical physicsSpecific orbital energyChemistry

摘要: The most usual difficulties encountered in the study of frontier-controlled reactions by approximate methods (aromaticity rules, frontier-orbital approximation and correlation diagram) are reviewed.

参考文章(41)
Michael James Steuart Dewar, Ralph C. Dougherty, The PMO Theory of Organic Chemistry ,(1975)
Chemical and biochemical reactivity Israel Academy of Sciences and Humanities. ,(1975) , 10.1007/978-94-010-1772-5
Jacqueline Langlet, Jean Paul Malrieu, Analysis of electrocyclic reactions using localized orbitals Journal of the American Chemical Society. ,vol. 94, pp. 7254- 7267 ,(1972) , 10.1021/JA00776A004
Timothy Clark, Paul v.R. Schleyer, Hydroboration; An ab initio study of the reaction of BH3 with ethylene Journal of Organometallic Chemistry. ,vol. 156, pp. 191- 202 ,(1978) , 10.1016/S0022-328X(00)84876-7
Jerome A. Berson, Orbital-symmetry-forbidden reactions Accounts of Chemical Research. ,vol. 5, pp. 406- 414 ,(1972) , 10.1021/AR50060A003