(Carbon dioxide)bis(trialkylphosphine)nickel complexes
作者： Michele Aresta , C. Francesco Nobile
DOI: 10.1039/DT9770000708
关键词: Nickel 、 Toluene 、 Carbon dioxide 、 Polymer chemistry 、 Inorganic chemistry 、 Tricyclohexylphosphine 、 Chemistry
摘要: The reaction of [NiL4](L = PEt3 or PBun3) with CO2 in toluene affords complexes formula [Ni(CO2)L2], via the [Ni(CO2)L3] species. [Ni(CO2){P(C6H11)3}2]·0.75C6H5Me O2 to give (peroxocarbonato)-bis( tricyclohexylphosphine)nickel(II) is also reported.
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