The chair conformation of C-methylcalix[4]resorcinarene in a novel, stepped, supramolecular framework

作者: Bao-Qing Ma , Yuegang Zhang , Philip Coppens

DOI: 10.1039/B103190M

关键词: ChemistryResorcinareneMolecular conformationStereochemistryHydrothermal synthesisSupramolecular chemistryCyclohexane conformationCrystallizationMolecule

摘要: The previously unobserved chair conformation of C-methylcalix[4]resorcinarene has been found in three different supramolecular solids, prepared by hydrothermal synthesis. existence the chair, crown and flattened cone conformations demonstrates dependence molecular upon templating molecules, specifics crystallization process. A novel, three-dimensional framework capable including guest molecules is described.

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