Orientation of water adsorbed on Cu(110)
作者： C. Mariani , K. Horn
DOI: 10.1016/0039-6028(83)90722-7
关键词: Dipole 、 Adsorption 、 Chemisorption 、 Copper 、 Monolayer 、 Molecule 、 Chemistry 、 Valence (chemistry) 、 Crystallography 、 Chemical physics 、 Metal
摘要: Abstract The method of determining the orientation an adsorbed molecule by angle-resolved photoemission with polarised light has been applied to case water on clean copper (110). By using dipole selection rules and symmetry arguments, it is found that in full monolayer as well at submonolayer coverages, molecules are a tilted geometry. Only small shifts valence peak relative gas phase spectrum found, indicative weak chemisorption bond. These results explained, recourse LEED observations, terms recent models layers metal surfaces.
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E. W. Plummer, W. Eberhardt, Angle-Resolved Photoemission as a Tool for the Study of Surfaces Advances in Chemical Physics. pp. 533- 656 ,(2007) , 10.1002/9780470142691.CH8
H. Ibach, S. Lehwald, The bonding of water molecules to platinum surfaces Surface Science. ,vol. 91, pp. 187- 197 ,(1980) , 10.1016/0039-6028(80)90079-5
K. Horn, A. M. Bradshaw, K. Jacobi, Angular‐resolved UPS studies of the chemisorption of ethylene and acetylene on nickel (100) Journal of Vacuum Science and Technology. ,vol. 15, pp. 575- 579 ,(1978) , 10.1116/1.569477
D. W. Turner, C. Baker, A. D. Baker, C. R. Brundle, David A. Shirley, Molecular Photoelectron Spectroscopy Physics Today. ,vol. 25, pp. 59- 60 ,(1972) , 10.1063/1.3070897
K. Bange, D. Grider, J.K. Sass, Coadsorption of water and ions on Cu(110): Models for the double layer Surface Science. ,vol. 126, pp. 437- 443 ,(1983) , 10.1016/0039-6028(83)90740-9
Theodore E. Madey, John T. Yates, Evidence for the conformation of H2O adsorbed on Ru(001) Chemical Physics Letters. ,vol. 51, pp. 77- 83 ,(1977) , 10.1016/0009-2614(77)85359-1
C. Benndorf, C. Nöbl, M. Rusenberg, F. Thieme, H2O interaction with clean and oxygen precovered Ni(110) Surface Science. ,vol. 111, pp. 87- 101 ,(1981) , 10.1016/0039-6028(81)90477-5
A. M. Bradshaw, M. Scheffler, Lateral interactions in adsorbed layers Journal of Vacuum Science and Technology. ,vol. 16, pp. 447- 454 ,(1979) , 10.1116/1.569976
Falko P. Netzer, Theodore E. Madey, Coadsorption-Induced Azimuthal Ordering in Molecular Adsorbate Layers:H2O and NH3on Oxygen-Precovered Ni(111) Physical Review Letters. ,vol. 47, pp. 928- 931 ,(1981) , 10.1103/PHYSREVLETT.47.928