Novel lanthanide complexes for visible and IR emission
作者： F. Rizzo , A. Papagni , F. Meinardi , R. Tubino , M. Ottonelli
DOI: 10.1016/J.SYNTHMET.2004.05.027
关键词: Antenna (radio) 、 Optical amplifier 、 Solubility 、 Photochemistry 、 Ion 、 Infrared spectroscopy 、 Lanthanide 、 Chemistry 、 Triplet state 、 Emission spectrum
摘要: In this work we report the synthesis and photophysical properties of a novel ligand its lanthanide complexes based on macrocycle 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid bearing 8-hydroxyquinoline as antenna. Visible IR sensitized emission is obtained because efficient energy transfer from antenna to emitting ion. The interaction between ions accounted for by suitable quantum chemical calculations. good stability their solubility in organic solvents make them candidates fabrication plastic waveguides optical amplifiers.
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sci-hub.se 参考文章(16)
Antônio V. M. De Andrade, Nivan B. Da Costa Jr., Ricardo L. Longo, Oscar L. Malta, Alfredo M. Simas, Gilberto F. De Sá, Modeling Lanthanide Complexes: Towards the Theoretical Design of Light Conversion Molecular Devices Molecular Engineering. ,vol. 7, pp. 293- 308 ,(1997) , 10.1023/A:1008227001656
Takaaki Ishigure, Eisuke Nihei, Yasuhiro Koike, Graded-index polymer optical fiber for high-speed data communication Applied Optics. ,vol. 33, pp. 4261- 4266 ,(1994) , 10.1364/AO.33.004261
Michael C. Zerner, Gilda H. Loew, Robert F. Kirchner, Ulrich T. Mueller-Westerhoff, An intermediate neglect of differential overlap technique for spectroscopy of transition-metal complexes. Ferrocene Journal of the American Chemical Society. ,vol. 102, pp. 589- 599 ,(1980) , 10.1021/JA00522A025
Joan E. Ridley, Michael C. Zerner, Triplet states via intermediate neglect of differential overlap: Benzene, pyridine and the diazines Theoretical Chemistry Accounts. ,vol. 42, pp. 223- 236 ,(1976) , 10.1007/BF00574445
W. T. Carnall, P. R. Fields, K. Rajnak, Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. II. Pm3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, and Ho3+ Journal of Chemical Physics. ,vol. 49, pp. 4412- 4423 ,(1968) , 10.1063/1.1669892
G. A. Crosby, R. E. Whan, R. M. Alire, Intramolecular Energy Transfer in Rare Earth Chelates. Role of the Triplet State The Journal of Chemical Physics. ,vol. 34, pp. 743- 748 ,(1961) , 10.1063/1.1731670
W. T. Carnall, P. R. Fields, K. Rajnak, Electronic Energy Levels in the Trivalent Lanthanide Aquo Ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+ Journal of Chemical Physics. ,vol. 49, pp. 4424- 4442 ,(1968) , 10.1063/1.1669893
Silvio Quici, Giovanni Marzanni, Marco Cavazzini, Pier Lucio Anelli, Mauro Botta, Eliana Gianolio, Gianluca Accorsi, Nicola Armaroli, Francesco Barigelletti, Highly Luminescent Eu3+ and Tb3+ Macrocyclic Complexes Bearing an Appended Phenanthroline Chromophore Inorganic Chemistry. ,vol. 41, pp. 2777- 2784 ,(2002) , 10.1021/IC025543J
Antônio V.M de Andrade, Nivan B da Costa, Oscar L Malta, Ricardo L Longo, Alfredo M Simas, Gilberto F de Sá, Excited state calculations of Europium(III) complexes Journal of Alloys and Compounds. ,vol. 250, pp. 412- 416 ,(1997) , 10.1016/S0925-8388(96)02560-1
W. M. Watson, Richard P. Zerger, James T. Yardley, Galen D. Stucky, Examination of photophysics in rare earth chelates by laser-excited luminescence Inorganic Chemistry. ,vol. 14, pp. 2675- 2680 ,(1975) , 10.1021/IC50153A016