Readily Prepared Dynamic Hydrogels by Combining Phenyl Boronic Acid‐ and Maltose‐Modified Anionic Polysaccharides at Neutral pH
作者： Dominte Tarus , Emilie Hachet , Léa Messager , Bogdan Catargi , Valérie Ravaine
关键词: Covalent bond 、 Aqueous solution 、 Polysaccharide 、 Self-healing hydrogels 、 Materials science 、 Phenylboronic acid 、 Organic chemistry 、 Boronic acid 、 Coupling reaction 、 Maltose
摘要: Dynamic covalent hydrogels are facilely prepared from biocompatible polysaccharides in physiological conditions by the formation of phenylboronate ester cross-links. This is based on simple mixing carboxylate-containing (i.e., hyaluronic acid or carboxymethylcellulose) modified with phenylboronic and maltose moieties according to mild coupling reactions performed aqueous solution. The dynamic networks reversible boronic-ester cross-links demonstrated analyzing their rheological behavior. study shows that these gels can adapt structure response chemical stimuli such as variations pH addition glucose self-heal.
sci-hub.se 参考文章(37)
Shigeru Kitano, Kazunori Kataoka, Yoshiyuki Koyama, Teruo Okano, Yasuhisa Sakurai, Glucose‐responsive complex formation between poly(vinyl alcohol) and poly(N‐vinyl‐2‐pyrrolidone) with pendent phenylboronic acid moieties Die Makromolekulare Chemie, Rapid Communications. ,vol. 12, pp. 227- 233 ,(1991) , 10.1002/MARC.1991.030120405
Badriprasad Ananthanarayanan, Yushan Kim, Sanjay Kumar, Elucidating the mechanobiology of malignant brain tumors using a brain matrix-mimetic hyaluronic acid hydrogel platform Biomaterials. ,vol. 32, pp. 7913- 7923 ,(2011) , 10.1016/J.BIOMATERIALS.2011.07.005
Marina V. Kuzimenkova, Alexander E. Ivanov, Chongdee Thammakhet, Lyubov I. Mikhalovska, Igor Yu. Galaev, Panote Thavarungkul, Proespichaya Kanatharana, Bo Mattiasson, Optical responses, permeability and diol-specific reactivity of thin polyacrylamide gels containing immobilized phenylboronic acid Polymer. ,vol. 49, pp. 1444- 1454 ,(2008) , 10.1016/J.POLYMER.2008.02.009
A.E. Ivanov, H. Larsson, I.Yu. Galaev, B. Mattiasson, Synthesis of boronate-contaming copolymers of N,N-dimethylacrylamide, their interaction with poly(vinyl alcohol) and rheological behaviour of the gels Polymer. ,vol. 45, pp. 2495- 2505 ,(2004) , 10.1016/J.POLYMER.2004.02.022
Bin Yang, Yaling Zhang, Xiaoyong Zhang, Lei Tao, Shuxi Li, Yen Wei, Facilely prepared inexpensive and biocompatible self-healing hydrogel: a new injectable cell therapy carrier Polymer Chemistry. ,vol. 3, pp. 3235- 3238 ,(2012) , 10.1039/C2PY20627G
Akira Matsumoto, Syuhei Ikeda, Atsushi Harada, Kazunori Kataoka, Glucose-responsive polymer bearing a novel phenylborate derivative as a glucose-sensing moiety operating at physiological pH conditions. Biomacromolecules. ,vol. 4, pp. 1410- 1416 ,(2003) , 10.1021/BM034139O
Marie Krogsgaard, Manja A. Behrens, Jan Skov Pedersen, Henrik Birkedal, Self-healing mussel-inspired multi-pH-responsive hydrogels. Biomacromolecules. ,vol. 14, pp. 297- 301 ,(2013) , 10.1021/BM301844U
Fei Cheng, Frieder Jäkle, Boron-containing polymers as versatile building blocks for functional nanostructured materials Polymer Chemistry. ,vol. 2, pp. 2122- 2132 ,(2011) , 10.1039/C1PY00123J
Takeshi Maeda, Hideyuki Otsuka, Atsushi Takahara, Dynamic covalent polymers: Reorganizable polymers with dynamic covalent bonds Progress in Polymer Science. ,vol. 34, pp. 581- 604 ,(2009) , 10.1016/J.PROGPOLYMSCI.2009.03.001
Greg Springsteen, Binghe Wang, A detailed examination of boronic acid–diol complexation Tetrahedron. ,vol. 58, pp. 5291- 5300 ,(2002) , 10.1016/S0040-4020(02)00489-1