Action des organomagnesiens allyliques sur quelques thiocetones cyclisation de thiols β,γ-ethyleniques
作者： M. Dagonneau , J. Vialle
DOI: 10.1016/S0040-4020(01)97016-4
关键词: Medicinal chemistry 、 Chemistry
摘要: Resume Les organomagnesiens allyliques reagissent sur les thiocetones R1R2CS (thiobenzophenone, thiopivalophenone, thiopinacolone, thiocamphre et thiofenchone) pour donner thiols β,γ-ethyleniques R1R2C(SH)-CHR-CHCH2. Ces composes conduisent par cyclisation radicalaire aux thiolannes substitues correspondants. proportions de diastereoisomeres (et d'isomeres subsequents) ont ete determinees dans un cas (thiopinacolone 4- bromure crotylmagnesium),
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