Coexistence of the soft mode and sub-THz central peak in ferroelectric BaTiO 3 /(Ba,Sr)TiO 3 superlattices

作者: A.G. Razumnaya , Yu.A. Tikhonov , Yu.I. Yuzyuk , I.N. Zakharchenko , V.I. Torgashev

DOI: 10.1016/J.SPMI.2015.07.038

关键词: Materials scienceHarmonic oscillatorDebyeSoft modesPhase transitionAtmospheric temperature rangeSuperlatticeRaman spectroscopyFerroelectricityCondensed matter physics

摘要: Abstract Near- and sub-Terahertz dynamics of soft Debye-type central modes was studied by the polarized Raman spectroscopy in ferroelectric BaTiO3/Ba0.3Sr0.7TiO3 (BT/BST) superlattice temperature range 80–400 K where system undergoes series phase transitions: paraelectric-tetragonal–monoclinic BT layers paraelectric-orthorhombic-monoclinic BST layers. It shown that evolution these can be described within model coexisted damped harmonic oscillator Debye relaxator. The occurrence pronounced mode explain recently observed relaxor-like dielectric anomaly such superlattice.

参考文章(35)
Igor Luk'yanchuk, Anaïs Sené, Alexey Pakhomov, Alexandr Sidorkin, Valerii Vinokur, Terahertz Electrodynamics of $180^\circ$ Domain Walls in Thin Ferroelectric Films arXiv: Materials Science. ,(2014)
DA Tenne, AM Clark, AR James, A Soukiassian, XX Xi, None, Lattice dynamics in BaxSr1-xTiO3 thin films studied by Raman spectroscopy Journal of Applied Physics. ,vol. 96, pp. 6597- 6605 ,(2004) , 10.1063/1.1806553
Sergey Lisenkov, L. Bellaiche, Phase diagrams of BaTiO3/SrTiO3 superlattices from first principles Physical Review B. ,vol. 76, ,(2007)
V. B. Shirokov, Yu. I. Yuzyuk, B. Dkhil, V. V. Lemanov, Phenomenological theory of phase transitions in epitaxial Ba x Sr 1 − x TiO 3 thin films Physical Review B. ,vol. 75, pp. 144118- ,(2007) , 10.1103/PHYSREVB.75.224116
V. V. Lemanov, E. P. Smirnova, P. P. Syrnikov, E. A. Tarakanov, Phase transitions and glasslike behavior inSr1−xBaxTiO3 Physical Review B. ,vol. 54, pp. 3151- 3157 ,(1996) , 10.1103/PHYSREVB.54.3151
Z.-G. Ban, S. P. Alpay, Phase diagrams and dielectric response of epitaxial barium strontium titanate films: A theoretical analysis Journal of Applied Physics. ,vol. 91, pp. 9288- 9296 ,(2002) , 10.1063/1.1473675
M. D. Fontana, G. E. Kugel, C. Carabatos-Nedelec, Comment on ‘‘Direct observation of relaxation modes inKNbO3andBaTiO3using inelastic light scattering’’ Physical Review B. ,vol. 40, pp. 786- 787 ,(1989) , 10.1103/PHYSREVB.40.786
Yu.I. Yuzyuk, A. Almeida, M.R. Chaves, V.A. Alyoshin, I.N. Zakharchenko, E.V. Sviridov, Soft Mode in Heteroepitaxial (Ba, Sr)TiO3MgO Thin Films Physica Status Solidi B-basic Solid State Physics. ,vol. 222, pp. 535- 540 ,(2000) , 10.1002/1521-3951(200011)222:2<535::AID-PSSB535>3.0.CO;2-P
R. Comes, M. Lambert, A. Guinier, The chain structure of BaTiO3 and KNbO3 Solid State Communications. ,vol. 6, pp. 715- 719 ,(1968) , 10.1016/0038-1098(68)90571-1
I. G. Siny, S. G. Lushnikov, R. S. Katiyar, E. A. Rogacheva, Central peak in light scattering from the relaxor ferroelectric PbMg 1 / 3 Nb 2 / 3 O 3 Physical Review B. ,vol. 56, pp. 7962- 7966 ,(1997) , 10.1103/PHYSREVB.56.7962