On charge transfer spectra
作者： R. Beukers , A. Szent-Györgyi
关键词: Series (mathematics) 、 Atomic physics 、 Acceptor 、 Charge (physics) 、 Chemistry 、 Spectral line 、 Computational chemistry 、 Polar 、 Electron 、 Absorption (electromagnetic radiation) 、 Maxima 、 General chemistry
摘要: The relationship between the maximum of absorption a donor-acceptor complex and P value relevant donor for series donors with same acceptor is reasonable linear. value, measure energy electron in highest filled orbital, has advantage being calculable many substances biological interest. still linear low values also complexes maxima near infrared. tested polar solvents. In case more than one formed, only obeys rule. Sometimes deviations observed are systematic, e.g. effect solvent cancelled when results two (two different acceptors) compared (Foster's rule).
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