Structural and magnetic properties of Mn3−xCdxTeO6 (x=0, 1, 1.5 and 2)

作者: S.A. Ivanov , R. Mathieu , P. Nordblad , E. Politova , R. Tellgren

DOI: 10.1016/J.JMMM.2011.12.027

关键词: Atmospheric temperature rangeCrystallographyCondensed matter physicsCeramicMagnetizationElectron microscopeTransition temperatureMaterials sciencePowder diffractionDopingMagnetic structure

摘要: Abstract Mn 3 TeO 6 exhibits a corundum-related A structure and complex magnetic involving two orbits for the atoms [Ivanov et al., 2011 [3] ]. 3− x Cd ( =0, 1, 1.5, 2) ceramics were synthesized by solid state reaction investigated using X-ray powder diffraction, electron microscopy, calorimetric measurements. 2+ replaces cations without greatly affecting of compound. The found to be randomly distributed over -site. Magnetization measurements indicated that samples order antiferromagnetically at low temperature with transition decreases increasing doping. nuclear one specially prepared 114 containing sample: 1.5 , was studied neutron diffraction range 2–295 K. in an incommensurate helical structure, very similar However, lower extension ordered confined 240(10) A.

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