Carbon dioxide activation: thermodynamics of CO2 binding and the involvement of two cobalt centers in the reduction of CO2 by a cobalt(I) macrocycle

作者： Etsuko. Fujita , David J. Szalda , Carol. Creutz , Norman. Sutin

关键词: Stereochemistry 、 Carbon dioxide 、 Acetonitrile 、 Chemistry 、 Diene 、 Spectroscopy 、 Medicinal chemistry 、 Chemical reaction 、 Compounds of carbon 、 Cobalt 、 Moiety

摘要: The interaction of CO/sub 2/ with the cobalt (I) macrocycle, CoL/sup +/ L = (14)diene 5,7,7,12,14,14-hexamethyl-1,4,8,11-reversible binding to in CH/sub 3/CN as characterized by uv-visible spectroscopy, a reduction solid state, binuclear species containing Co-C(OH)-O-Co moiety are described this article. 22 references, 2 figures.

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Carbon dioxide activation: thermodynamics of CO2 binding and the involvement of two cobalt centers in the reduction of CO2 by a cobalt(I) macrocycle

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Carbon dioxide activation: thermodynamics of CO2 binding and the involvement of two cobalt centers in the reduction of CO2 by a cobalt(I) macrocycle

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