A crosslinkable polyethylene composition, method of making the same, and articles made therefrom
作者： Bharat I. Chaudhary , John Klier
DOI:
关键词: Polymer chemistry 、 Alkadiene 、 Melt blending 、 Double bond 、 Organic chemistry 、 Organic peroxide 、 Materials science 、 Thermal decomposition 、 Polyethylene
摘要: The instant invention is a crosslinkable polyethylene composition, method of making the same, and articles made therefrom. composition according to includes component, crosslinking agent, coagent. agent an organic peroxide, coagent alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds. may, optionally, further include scorch inhibitor, cure booster, stable free radical, one more conventional additives, blends thereof, and/or combinations thereof. for producing steps of: (1) providing component; (2) wherein peroxide; (3) coagent, bonds; (4) melt blending temperature in range less than decomposition agent; (5) thereby forming composition. article crosslinked product
lens.org参考文章(17)
Michael John Keogh, A crosslinkable polyethylene composition ,(2000)
Jeffrey M. Cogen, Jinder Jow, Bharat I. Chaudhary, Mohamed Esseghir, Robert F. Eaton, John Klier, Suzanne M. Guerra, Nitroxide compounds for minimizing scorch in crosslinkable compositions ,(2007)
Olivier Guerret, Jacques Kervennal, Alfredo Defrancisci, Fabien Debaud, Scorch-retardant composition ,(2005)
Olivier Guerret, Jacques Kervennal, Alfredo Defrancisci, Fabien Debaud, Scorch-delaying composition ,(2005)
Lonnie G. Hazlitt, Daniel G. Moldovan, High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers ,(1987)
Takanori Yamazaki, Tadao Seguchi, Electron spin resonance study on chemical‐crosslinking reaction mechanisms of polyethylene using a chemical agent. VI. Effect of α‐methyl styrene dimer Journal of Polymer Science Part A. ,vol. 39, pp. 2151- 2156 ,(2001) , 10.1002/POLA.1191
James C. Randall, A REVIEW OF HIGH RESOLUTION LIQUID 13CARBON NUCLEAR MAGNETIC RESONANCE CHARACTERIZATIONS OF ETHYLENE-BASED POLYMERS Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics. ,vol. 29, pp. 201- 317 ,(1989) , 10.1080/07366578908055172
M Palmlöf, T Hjertberg, Crosslinking of poly(ethylene-co-1,9-decadiene) by electron beam irradiation Polymer. ,vol. 41, pp. 6481- 6495 ,(2000) , 10.1016/S0032-3861(99)00882-4
M Palmlöf, T Hjertberg, Chemical and mechanical changes in poly(ethylene-co-1,9-decadiene) following crosslinking induced by peroxides Polymer. ,vol. 41, pp. 6497- 6505 ,(2000) , 10.1016/S0032-3861(99)00881-2
B. Gustafsson, J.-O. Boström, R. C. Dammert, Stabilization of peroxide crosslinked polyethylene Angewandte Makromolekulare Chemie. ,vol. 261, pp. 93- 99 ,(1998) , 10.1002/(SICI)1522-9505(19981201)261-262:1<93::AID-APMC93>3.0.CO;2-Y