Diffusion in polymer—solvent systems. I. Reexamination of the free‐volume theory

作者: J. S. Vrentas , J. L. Duda

DOI: 10.1002/POL.1977.180150302

关键词: ThermodynamicsDiffusion theorySolventChemistryFree volume theorySolvent systemDiffusion (business)Volume (thermodynamics)PolymerFujita scale

摘要: … Furthermore, we call the free volume associated with the … free volume, and we assume that this free volume can be redistributed with no increase in energy. Since the hole free volume is …

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