OCO and NCO chelated derivatives of heavier group 15 elements. Study on possibility of cyclization reaction via intramolecular ether bond cleavage.

作者: Libor Dostál , Roman Jambor , Aleš Růžička , Robert Jirásko , Jaroslav Holeček

DOI: 10.1039/C1DT10234F

关键词: EtherIntramolecular forceIonic bondingStereochemistryBond cleavageCrystal structureMedicinal chemistryChemistryChloridePincer movementLigand

摘要: … ]PCl (1) as a result of intramolecular ether bond cleavage and elimination of t-BuCl. The … (9), are stable without any indication for etheral bond cleavage. The situation is rather similar in …

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