Thermal and Fluctuation-Induced Deformations of Chemical Bonds in Surface and Boundary Layers of Polymers
作者： V. I. Vettegren
DOI: 10.1134/1.1924856
关键词: Molecule 、 Free surface 、 Solid-state physics 、 Polymer 、 Deformation (engineering) 、 Supramolecular chemistry 、 Chemical bond 、 Chemical physics 、 Materials science 、 Raman spectroscopy 、 Electronic, Optical and Magnetic Materials 、 Condensed matter physics
摘要: The deformation of chemical bonds in polymer molecules surface layers samples, boundary between supramolecular aggregates, and polymers solids composites is investigated using IR Raman spectroscopy. It found that the are elongated on a free aggregates. By contrast, contracted solids. concentration strain excited (strained to approximately theoretical ultimate elongation) increased whereas decreased. These effects explained by changes atomic vibrations layers.
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