DNA-Assisted β-phase Nucleation and Alignment of Molecular Dipoles in PVDF Film: A Realization of Self-Poled Bioinspired Flexible Polymer Nanogenerator for Portable Electronic Devices

作者: Abiral Tamang , Sujoy Kumar Ghosh , Samiran Garain , Md. Mehebub Alam , Jörg Haeberle

DOI: 10.1021/ACSAMI.5B04161

关键词: ElectrodePolymerEnergy conversion efficiencyPolingNanogeneratorNucleationCapacitorPiezoelectricityMaterials scienceNanotechnology

摘要: A flexible nanogenerator (NG) is fabricated with a poly(vinylidene fluoride) (PVDF) film, where deoxyribonucleic acid (DNA) the agent for electroactive β-phase nucleation. Denatured DNA co-operating to align molecular −CH2/–CF2 dipoles of PVDF causing piezoelectricity without electrical poling. The NG capable harvesting energy from variety easily accessible mechanical stress such as human touch, machine vibration, football juggling, and walking. exhibits high piezoelectric conversion efficiency facilitating instant turn-on several green or blue light-emitting diodes. generated can be used charge capacitors providing wide scope design self-powered portable devices.

参考文章(27)
Ya Yang, Hulin Zhang, Jun Chen, Sangmin Lee, Te-Chien Hou, Zhong Lin Wang, Simultaneously harvesting mechanical and chemical energies by a hybrid cell for self-powered biosensors and personal electronics Energy and Environmental Science. ,vol. 6, pp. 1744- 1749 ,(2013) , 10.1039/C3EE40764K
Zdeňka Malá, Karel Klepárnı́k, Petr Boček, Highly alkaline electrolyte for single-stranded DNA separations by electrophoresis in bare silica capillaries. Journal of Chromatography A. ,vol. 853, pp. 371- 379 ,(1999) , 10.1016/S0021-9673(99)00476-8
Pejman Talemi, Marine Delaigue, Peter Murphy, Manrico Fabretto, Flexible polymer-on-polymer architecture for piezo/pyroelectric energy harvesting ACS Applied Materials & Interfaces. ,vol. 7, pp. 8465- 8471 ,(2015) , 10.1021/AM5089082
Dipankar Mandal, Karsten Henkel, Dieter Schmeißer, Improved performance of a polymer nanogenerator based on silver nanoparticles doped electrospun P(VDF–HFP) nanofibers Physical Chemistry Chemical Physics. ,vol. 16, pp. 10403- 10407 ,(2014) , 10.1039/C3CP55238A
Toshiaki Ohta, Kazuhiko Seki, Toshihiko Yokoyama, Ikuo Morisada, Kunishige Edamatsu, Polarized XANES studies of oriented polyethylene and fluorinated polyethylenes Physica Scripta. ,vol. 41, pp. 150- 153 ,(1990) , 10.1088/0031-8949/41/1/036
Subrata Maji, Piyush Kanti Sarkar, Leena Aggarwal, Sujoy Kumar Ghosh, Dipankar Mandal, Goutam Sheet, Somobrata Acharya, Self-oriented β-crystalline phase in the polyvinylidene fluoride ferroelectric and piezo-sensitive ultrathin Langmuir-Schaefer film. Physical Chemistry Chemical Physics. ,vol. 17, pp. 8159- 8165 ,(2015) , 10.1039/C5CP00218D
Md Mehebub Alam, Sujoy Kumar Ghosh, Ayesha Sultana, Dipankar Mandal, Lead-free ZnSnO3/MWCNTs-based self-poled flexible hybrid nanogenerator for piezoelectric power generation. Nanotechnology. ,vol. 26, pp. 165403- ,(2015) , 10.1088/0957-4484/26/16/165403
P. Martins, A.C. Lopes, S. Lanceros-Mendez, Electroactive phases of poly(vinylidene fluoride) : determination, processing and applications Progress in Polymer Science. ,vol. 39, pp. 683- 706 ,(2014) , 10.1016/J.PROGPOLYMSCI.2013.07.006
Prakriti Adhikary, Samiran Garain, Dipankar Mandal, The co-operative performance of a hydrated salt assisted sponge like P(VDF-HFP) piezoelectric generator: an effective piezoelectric based energy harvester. Physical Chemistry Chemical Physics. ,vol. 17, pp. 7275- 7281 ,(2015) , 10.1039/C4CP05513F