The permanent electric dipole moment and hyperfine interactions in platinum monofluoride, PtF

摘要: The [11.9]Ω = 3/2 ← X 2Π3/2(0,0) and (1,0) bands of platinum monofluoride, PtF, have been recorded field-free in the presence a static electric field. 19F(I 1/2) 195Pt(I magnetic hyperfine interactions analyzed compared with predicted values obtained using atomic information proposed molecular orbital correlation diagram. optical Stark shifts were to produce permanent dipole moments, μel, 2.47(11)D 3.42(6)D for 2Π3/2states, respectively. observed trend μel PtX (X C,N,O,S F) series is discussed comparison IrF made.