A composite of Co nanoparticles highly dispersed on N-rich carbon substrates: an efficient electrocatalyst for Li–O2 battery cathodes
作者： Zhang Zhang , Liwei Su , Mei Yang , Meng Hu , Jie Bao
DOI: 10.1039/C3CC47149G
关键词: Carbon 、 Overpotential 、 Battery (electricity) 、 Cathode catalyst 、 Cathode 、 Electrocatalyst 、 Chemical engineering 、 Nanoparticle 、 Composite number 、 Materials science
摘要: In this work, we present a facile sol–gel method to prepare composite of Co nanoparticles highly dispersed on N-rich carbon substrates (Co–C composite). The assembled Li–O2 batteries with the as cathode catalyst showed lower overpotential and better cyclability, improved performance may be attributed superior electrocatalytic activity Co–C composite.
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sci-hub.se 参考文章(29)
Zhen-Huan Sheng, Lin Shao, Jing-Jing Chen, Wen-Jing Bao, Feng-Bin Wang, Xing-Hua Xia, Catalyst-Free Synthesis of Nitrogen-Doped Graphene via Thermal Annealing Graphite Oxide with Melamine and Its Excellent Electrocatalysis ACS Nano. ,vol. 5, pp. 4350- 4358 ,(2011) , 10.1021/NN103584T
G. Q. Zhang, J. P. Zheng, R. Liang, C. Zhang, B. Wang, M. Hendrickson, E. J. Plichta, Lithium–Air Batteries Using SWNT/CNF Buckypapers as Air Electrodes Journal of The Electrochemical Society. ,vol. 157, ,(2010) , 10.1149/1.3446852
Stefan A. Freunberger, Yuhui Chen, Zhangquan Peng, John M. Griffin, Laurence J. Hardwick, Fanny Bardé, Petr Novák, Peter G. Bruce, Reactions in the Rechargeable Lithium–O2 Battery with Alkyl Carbonate Electrolytes Journal of the American Chemical Society. ,vol. 133, pp. 8040- 8047 ,(2011) , 10.1021/JA2021747
Jie Xiao, Donghai Mei, Xiaolin Li, Wu Xu, Deyu Wang, Gordon L. Graff, Wendy D. Bennett, Zimin Nie, Laxmikant V. Saraf, Ilhan A. Aksay, Jun Liu, Ji-Guang Zhang, Hierarchically porous graphene as a lithium-air battery electrode. Nano Letters. ,vol. 11, pp. 5071- 5078 ,(2011) , 10.1021/NL203332E
Stefan A. Freunberger, Yuhui Chen, Nicholas E. Drewett, Laurence J. Hardwick, Fanny Bardé, Peter G. Bruce, The Lithium–Oxygen Battery with Ether‐Based Electrolytes Angewandte Chemie. ,vol. 50, pp. 8609- 8613 ,(2011) , 10.1002/ANIE.201102357
Muhammed M. Ottakam Thotiyl, Stefan A. Freunberger, Zhangquan Peng, Yuhui Chen, Zheng Liu, Peter G. Bruce, A stable cathode for the aprotic Li–O2 battery Nature Materials. ,vol. 12, pp. 1050- 1056 ,(2013) , 10.1038/NMAT3737
Wei Yang, Jason Salim, Chao Ma, Zhaohui Ma, Chunwen Sun, Jianqi Li, Liquan Chen, Youngsik Kim, Flowerlike Co3O4 microspheres loaded with copper nanoparticle as an efficient bifunctional catalyst for lithium–air batteries Electrochemistry Communications. ,vol. 28, pp. 13- 16 ,(2013) , 10.1016/J.ELECOM.2012.12.007
Si Hyoung Oh, Robert Black, Ekaterina Pomerantseva, Jin-Hyon Lee, Linda F. Nazar, Synthesis of a metallic mesoporous pyrochlore as a catalyst for lithium–O2 batteries Nature Chemistry. ,vol. 4, pp. 1004- 1010 ,(2012) , 10.1038/NCHEM.1499
Robert Black, Si Hyoung Oh, Jin-Hyon Lee, Taeeun Yim, Brian Adams, Linda F. Nazar, Screening for Superoxide Reactivity in Li-O2 Batteries: Effect on Li2O2/LiOH Crystallization Journal of the American Chemical Society. ,vol. 134, pp. 2902- 2905 ,(2012) , 10.1021/JA2111543
Yongliang Li, Jiajun Wang, Xifei Li, Dongsheng Geng, Ruying Li, Xueling Sun, Superior energy capacity of graphene nanosheets for a nonaqueous lithium-oxygen battery Chemical Communications. ,vol. 47, pp. 9438- 9440 ,(2011) , 10.1039/C1CC13464G