Enzymatic carboxylation of hydroxystilbenes by the γ-resorcylic acid decarboxylase from Rhizobium radiobacter WU-0108 under reverse reaction conditions
作者： Masaru Sato , Nozomu Sakurai , Hideyuki Suzuki , Daisuke Shibata , Kuniki Kino
DOI: 10.1016/J.MOLCATB.2015.10.006
关键词: Organic chemistry 、 Benzoic acid 、 Carboxylation 、 Resorcinol 、 Enzyme 、 Resveratrol 、 Chemistry 、 Catechol 、 Piceatannol 、 Moiety
摘要: Abstract We examined 66 aromatics for carboxylation by the γ-resorcylic acid decarboxylase from Rhizobium radiobacter WU-0108 under reverse reaction conditions. The enzyme carboxylated resorcinol, catechol, 5-methylresorcinol and three hydroxystilbenes (resveratrol, gnetol, piceatannol) with high yields. Except structures of these substrates include a 1,3-dihydroxybenzene moiety. Other compounds gave no products. products resveratrol gnetol were 2,6-dihydroxy-4-[(E)-2-(4-hydroxyphenyl)ethenyl]benzoic 2,6-dihydroxy-4-[(E)-2-(2,6-dihydroxyphenyl)ethenyl]benzoic acid, respectively, as determined mass spectrometry nuclear magnetic resonance analyses. Kinetic analyses reactions indicated that are better than resorcinol or catechol.
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