Structural and Electrical Characterizations of Electrodeposited p-Type Semiconductor Cu2O Films

作者: Kotaro Mizuno , Masanobu Izaki , Kuniaki Murase , Tsutomu Shinagawa , Masaya Chigane

DOI: 10.1149/1.1862478

关键词:

摘要: The p-type semiconductor cuprous oxide (Cu 2 O) film has been of considerable interest as a component solar cells and photodiodes due to its bandgap energy 2.1 eV high optical absorption coefficient. We prepared Cu O films on conductive substrate by electrodeposition at 318 K from an aqueous solution containing copper sulfate lactic acid. structural electrical characterizations the resulting were examined X-ray diffraction, photoelectron spectroscopy, measurements, Hall effect measurement, respectively. resistivity varied 2.7 × 10 4 3.3 X 6 Ω cm, while carrier density was 1 cm - 3 mobility 0.4 1.8 V s , depending preparation conditions, i.e., pH deposition potential. sensitive atomic ratio in grain size.

参考文章(14)
Masanobu Izaki, Seiji Watase, Hisaya Takahashi, Room-temperature ultraviolet light-emitting zinc oxide micropatterns prepared by low-temperature electrodeposition and photoresist Applied Physics Letters. ,vol. 83, pp. 4930- 4932 ,(2003) , 10.1063/1.1633677
Masanobu Izaki, Takashi Omi, Transparent zinc oxide films prepared by electrochemical reaction Applied Physics Letters. ,vol. 68, pp. 2439- 2440 ,(1996) , 10.1063/1.116160
Sophie Peulon, Daniel Lincot, Cathodic electrodeposition from aqueous solution of dense or open‐structured zinc oxide films Advanced Materials. ,vol. 8, pp. 166- 170 ,(1996) , 10.1002/ADMA.19960080216
Masao Miyake, Kuniaki Murase, Tetsuji Hirato, Yasuhiro Awakura, Hall effect measurements on CdTe layers electrodeposited from acidic aqueous electrolyte Journal of Electroanalytical Chemistry. ,vol. 562, pp. 247- 253 ,(2004) , 10.1016/J.JELECHEM.2003.09.008
Feng‐Bin Li, G. E. Thompson, In Situ Atomic Force Microscopy Studies of the Deposition of Cerium Oxide Films on Regularly Corrugated Surfaces Journal of The Electrochemical Society. ,vol. 146, pp. 1809- 1815 ,(1999) , 10.1149/1.1391848
Eric W. Bohannan, Mark G. Shumsky, Jay A. Switzer, Epitaxial Electrodeposition of Copper(I) Oxide on Single-Crystal Gold(100) Chemistry of Materials. ,vol. 11, pp. 2289- 2291 ,(1999) , 10.1021/CM990304O
Shogo Ishizuka, Takahiro Maruyama, Katsuhiro Akimoto, Thin-Film Deposition of Cu2O by Reactive Radio-Frequency Magnetron Sputtering Japanese Journal of Applied Physics. ,vol. 39, ,(2000) , 10.1143/JJAP.39.L786
Lung Shan Kau, Darlene J Spira-Solomon, James E Penner-Hahn, Keith O Hodgson, Edward I Solomon, None, X-ray absorption edge determination of the oxidation state and coordination number of copper: application to the type 3 site in Rhus vernicifera laccase and its reaction with oxygen Journal of the American Chemical Society. ,vol. 109, pp. 6433- 6442 ,(1987) , 10.1021/JA00255A032
Hideki Matsumura, Asako Fujii, Tomohiro Kitatani, Properties of High-Mobility Cu2O Films Prepared by Thermal Oxidation of Cu at Low Temperatures. Japanese Journal of Applied Physics. ,vol. 35, pp. 5631- 5636 ,(1996) , 10.1143/JJAP.35.5631
A. J. Aldykiewicz, A. J. Davenport, H. S. Isaacs, Studies of the Formation of Cerium‐Rich Protective Films Using X‐Ray Absorption Near‐Edge Spectroscopy and Rotating Disk Electrode Methods Journal of The Electrochemical Society. ,vol. 143, pp. 147- 154 ,(1996) , 10.1149/1.1836400