The ground-state rotational spectrum of cyclopropyl silane
作者： Volker Typke
DOI: 10.1016/0022-2852(79)90203-0
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摘要: Abstract The rotational spectrum of cyclopropyl silane has been recorded in the region 9.0–35.0 GHz. Eighty-eight transitions ground vibrational state were measured and analyzed to give constants centrifugal distortion constants. dipole moment was determined be μ a = 0.847(17)D, c 0.273(10)D, tot 0.890(18)D. are consistent with shortening C bond length opposite silyl group. Since no splittings due internal rotation observed, lower limit for hindering potential group is V 3 ≥ 1950cal/mole.
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