MIXTURE EFFECTS IN DEEP CATALYTIC OXIDATION OF ETHANOL OVER PLATINUM. INFLUENCE OF BENZENE AND ETHENYLBENZENE ON RATE AND SELECTIVITY
作者： ANTONELLO A. BARRESI† , GIANCARLO BALDI
DOI: 10.1080/00986449308936163
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摘要: Abstract Mixture effects are observed when ethanol is oxidized in mixture with benzene or elhenylbenzene (styrcne). Very lean mixtures (<2000ppmV) were tested over a commercial monolithic catalyst. In the mass transfer controlled regime higher conversions obtained for aromatic, due to increased adiabatic temperature rise; but ignition increased. The hydrocarbon reaction rate slightly affected, while oxidation (either complete partial) strongly inhibited, especially by elhenylbenzene. selectivity of modified, significant reduction aldehyde emissions all range mainly strong inhibition at low and
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sci-hub.se 参考文章(13)
G. I. Golodet︠s︡, Heterogeneous catalytic reactions involving molecular oxygen ,(1983)
Richard D. Gonzalez, Masatoshi Nagaia, Oxidation of ethanol on silica supported noble metal and bimetallic catalysts Applied Catalysis. ,vol. 18, pp. 57- 70 ,(1985) , 10.1016/S0166-9834(00)80299-7
Antonello A. Barresi, Giancarlo Baldi, Deep catalytic oxidation kinetics of benzene-ethenylbenzene mixtures Chemical Engineering Science. ,vol. 47, pp. 1943- 1953 ,(1992) , 10.1016/0009-2509(92)80312-Z
ANTONELLO A. BARRESI†, GIANCARLO BALDI, Reaction mechanisms of ethanol deep oxidation over platinum catalyst Chemical Engineering Communications. ,vol. 123, pp. 17- 29 ,(1993) , 10.1080/00986449308936162
Bruce A. Tichenor, Michael A. Palazzolo, Destruction of volatile organic compounds via catalytic incineration Environmental Progress. ,vol. 6, pp. 172- 176 ,(1987) , 10.1002/EP.670060328
S.K. Gangwal, M.E. Mullins, J.J. Spivey, P.R. Caffrey, B.A. Tichenor, Kinetics and Selectivity of Deep Catalytic Oxidation of n-Hexane and Benzene Applied Catalysis. ,vol. 36, pp. 231- 247 ,(1988) , 10.1016/S0166-9834(00)80118-9
Antonello A. Barresi, Italo Mazzarino, Giancarlo Baldi, Gas phase complete catalytic oxidation of aromatic hydrocarbon mixtures Canadian Journal of Chemical Engineering. ,vol. 70, pp. 286- 293 ,(1992) , 10.1002/CJCE.5450700211
Masatoshi Nagai, Richard D. Gonzalez, Oxidation of ethanol and acetaldehyde on silica-supported platinum catalysts: preparative and pretreatment effects on catalyst selectivity Industrial & Engineering Chemistry Product Research and Development. ,vol. 24, pp. 525- 531 ,(1985) , 10.1021/I300020A008
J. J. Spivey, Complete catalytic oxidation of volatile organics Catalysis. ,vol. 26, pp. 157- 204 ,(1987) , 10.1039/9781847553201-00157
Sterling E. Voltz, Charles R. Morgan, David Liederman, Solomon M. Jacob, Kinetic Study of Carbon Monoxide and Propylene Oxidation on Platinum Catalysts Industrial & Engineering Chemistry Product Research and Development. ,vol. 12, pp. 294- 301 ,(1973) , 10.1021/I360048A006