Coordination and electrochemistry of new substituted manganese phthalocyanines
作者： Olga Dolotova , Alexandr Konarev , Konstantin Volkov , Vladimir Negrimovsky , Oleg L. Kaliya
DOI: 10.1142/S1088424612501015
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摘要: A number of substituted manganese phthalocyanines PcMn have been synthesized from the corresponding phthalonitriles with rather good yields (up to 67%) and high purity. All complexes were characterized by elemental analysis, electronic absorption spectra, some them redox potentials. Three coordination forms — PcMn(II), PcMn(III)X (LPcMn(III))2O fixed for all complexes. The equilibrium three isomers Pc +· Mn(I) × L, PcMn(II) Ln -· Mn(III) 2L has observed in solutions presence organic base L.
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