Synthesis and photophysical properties of pyrrole/polycyclic aromatic units hybrid fluorophores.
作者： Chang-Shun Li , Ya-Hsuan Tsai , Wei-Chen Lee , Wen-Jang Kuo
DOI: 10.1021/JO100158A
关键词:
摘要: A series of pyrrole/polycyclic aromatic unit hybrid fluorophores was developed by a two-stage synthetic strategy. Their central aryl-substituted pyrrole cores were constructed Paal−Knorr synthesis reaction. The reaction conditions and mechanism are also discussed in detail. End-capping triflate onto the core enables to incorporate various polycyclic units. Buchwald−Hartwig amination Suzuki−Miyaura cross-coupling adopted end-capping with N-phenylnaphthalen-1-amine units form fluorophores. photophysical properties thermal characterized. Most emitted blue light exhibited high quantum efficiency. fluorescence these induced manipulating surrounding When incorporated wit...
acs.org
core.ac.uk 
sci-hub.se 参考文章(85)
Jiuyan Li, Chunwah Ma, Jianxin Tang, Chun-Sing Lee, Shuittong Lee, Novel Starburst Molecule as a Hole Injecting and Transporting Material for Organic Light-Emitting Devices Chemistry of Materials. ,vol. 17, pp. 615- 619 ,(2005) , 10.1021/CM048337D
Qingguo Wu, James A. Lavigne, Ye Tao, Marie D'Iorio, Suning Wang, Novel blue luminescent/electroluminescent 7-azaindole derivatives: 1,3-Di(N-7-azaindolyl)benzene, 1-bromo-3,5-Di(N-7-azaindolyl)benzene, 1,3,5-Tri(N-7-azaindolyl)benzene, and 4,4'-Di(N-7-azaindolyl)biphenyl Chemistry of Materials. ,vol. 13, pp. 71- 77 ,(2001) , 10.1021/CM0007149
Chuanjun Xia, Rigoberto C. Advincula, Decreased Aggregation Phenomena in Polyfluorenes by Introducing Carbazole Copolymer Units Macromolecules. ,vol. 34, pp. 5854- 5859 ,(2001) , 10.1021/MA002036H
Jimmy Bouchard, Salem Wakim, Mario Leclerc, Synthesis of diindolocarbazoles by Cadogan reaction: route to ladder oligo(p-aniline)s. Journal of Organic Chemistry. ,vol. 69, pp. 5705- 5711 ,(2004) , 10.1021/JO049419O
Adam F. Littke, Chaoyang Dai, Gregory C. Fu, Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions Journal of the American Chemical Society. ,vol. 122, pp. 4020- 4028 ,(2000) , 10.1021/JA0002058
Chung-Wen Ko, Yu-Tai Tao, Jiann T. Lin, K. R. Justin Thomas, Light-Emitting Diodes Based on a Carbazole-Derivatized Dopant: Origin of Dopant Excitation as a Function of the Device Structure Chemistry of Materials. ,vol. 14, pp. 357- 361 ,(2002) , 10.1021/CM0106365
Takayuki Ohe, Norio Miyaura, Akira Suzuki, Palladium-catalyzed cross-coupling reaction of organoboron compounds with organic triflates Journal of Organic Chemistry. ,vol. 58, pp. 2201- 2208 ,(1993) , 10.1021/JO00060A041
Sujeewa S. Palayangoda, Xichen Cai, Ravi M. Adhikari, Douglas C. Neckers, Carbazole-based donor-acceptor compounds: highly fluorescent organic nanoparticles. Organic Letters. ,vol. 10, pp. 281- 284 ,(2008) , 10.1021/OL702666G
Norio. Miyaura, Akira. Suzuki, Palladium-catalyzed cross-coupling reactions of organoboron compounds Chemical Reviews. ,vol. 95, pp. 2457- 2483 ,(1995) , 10.1021/CR00039A007
Wen-Jian Shen, Rajasekhar Dodda, Chang-Ching Wu, Fang-Iy Wu, Tswen-Hsin Liu, Hsian-Hung Chen, Chin H. Chen, Ching-Fong Shu, Spirobifluorene-linked bisanthracene: An efficient blue emitter with pronounced thermal stability Chemistry of Materials. ,vol. 16, pp. 930- 934 ,(2004) , 10.1021/CM0345117