Blends of poly(ethylene oxide) and poly(4-vinylphenol-co-2-hydroxyethyl methacrylate): thermal analysis, morphological behaviour and specific interactions

作者: Ana Maria Rocco , C.E Bielschowsky , Robson Pacheco Pereira

DOI: 10.1016/S0032-3861(02)00786-3

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摘要: DSC and optical microscopy were used to determine the miscibility crystallinity of blends poly(ethylene oxide) (PEO) with poly(4-vinylphenol-co-2-hydroxyethyl methacrylate) (PVPh-HEM). A single glass transition temperature was observed for all blends, indicating miscibility. progressive decrease in degree size PEO spherullites is observed, as PVPh-HEM added. FTIR probe intermolecular specific interactions blend mainly attributed PVPh-HEM/PEO via hydrogen bonding.

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