Analyse conformationnelle theorique des complexes acide-base de lewis: III. Une approche semi-empirique (méthode CNDO/2) des geométries et de l'analyse conformationnelle du borazane et de ses dérives perfluoré
作者： Marie-Chantal Bach , Francois Crasnier , Jean-François Labarre , Claude Leibovici
DOI: 10.1016/0022-2860(73)80044-4
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摘要: Abstract The optimized geometries and theoretical data from conformational analysis cf borazane its perfluoro derivatives are investigated within the framework of CNDO/2 approximation. effect that fluorination has on geometrical electronic parameters series compounds is pointed out authors offer an explanation for anomalous behaviour H 3 N.BF . Furthermore, it shown assumption tetragonal hybridization N B atoms any incorrect if F molecule used as Lewis base.
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