A hybrid enzymatic zinc-air fuel cell
作者： Mohd Firdaus Abd Wahab , Faridah Yusof , Abdul Aziz Ahmad , Raihan Othman
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摘要: A hybrid biofuel cell, a zinc-air cell employing laccase as the oxygen reduction catalyst is investigated. simple design employed; membraneless single chamber and freely suspended in buffer electrolyte. The is characterised based on its open-circuit voltage, power density profile galvanostatic discharge at 0.5 mA. activity of an oxidoreductase substantiated from profiles. use air electrode design enhanced energy output by 14%. registered voltage 1.2 V capable to deliver maximum 1.1 mWcm-2 0.4 V. Despite features, comparable that biocatalytic utilising much more complex system design.
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Peter F. Connolly, Robert P. Hamlen, Metal/air-batteries ,(1986)
Miguel Alcalde, Laccases: Biological Functions, Molecular Structure and Industrial Applications Springer, Dordrecht. pp. 461- 476 ,(2007) , 10.1007/1-4020-5377-0_26
Javier Martinez-Ortiz, Roberto Flores, Rafael Vazquez-Duhalt, Molecular design of laccase cathode for direct electron transfer in a biofuel cell Biosensors and Bioelectronics. ,vol. 26, pp. 2626- 2631 ,(2011) , 10.1016/J.BIOS.2010.11.022
Maria Smolander, Harry Boer, Matti Valkiainen, Robert Roozeman, Mikael Bergelin, Jan-Erik Eriksson, Xia-Chang Zhang, Anu Koivula, Liisa Viikari, Development of a printable laccase-based biocathode for fuel cell applications Enzyme and Microbial Technology. ,vol. 43, pp. 93- 102 ,(2008) , 10.1016/J.ENZMICTEC.2007.11.019
A. Habrioux, G. Merle, K. Servat, K.B. Kokoh, C. Innocent, M. Cretin, S. Tingry, Concentric glucose/O2 biofuel cell Journal of Electroanalytical Chemistry. ,vol. 622, pp. 97- 102 ,(2008) , 10.1016/J.JELECHEM.2008.05.011
C. Chakkaravarthy, A.K.Abdul Waheed, H.V.K. Udupa, Zinc—air alkaline batteries — A review Journal of Power Sources. ,vol. 6, pp. 203- 228 ,(1981) , 10.1016/0378-7753(81)80027-4
Hyunsoo Moon, In Seop Chang, Byung Hong Kim, Continuous electricity production from artificial wastewater using a mediator-less microbial fuel cell. Bioresource Technology. ,vol. 97, pp. 621- 627 ,(2006) , 10.1016/J.BIORTECH.2005.03.027
C. F. Thurston, The structure and function of fungal laccases Microbiology. ,vol. 140, pp. 19- 26 ,(1994) , 10.1099/13500872-140-1-19
R. Othman, W.J. Basirun, A.H. Yahaya, A.K. Arof, Hydroponics gel as a new electrolyte gelling agent for alkaline zinc–air cells Journal of Power Sources. ,vol. 103, pp. 34- 41 ,(2001) , 10.1016/S0378-7753(01)00823-0
A. Kozawa, V. E. Zilionis, R. J. Brodd, Electrode Materials and Catalysts for Oxygen Reduction in Isotonic Saline Solution Journal of The Electrochemical Society. ,vol. 117, pp. 1474- 1478 ,(1970) , 10.1149/1.2407355