Ac conductivity of poly(o-methoxyaniline)

作者: J.S. Nogueira , L.H.C. Mattoso , R.M. Faria

DOI: 10.1109/ISE.1996.578060

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摘要: The AC conductivity of doped poly(o-methoxyaniline) (POMA) films, at temperatures between 4.2 and 298 K has been measured. For low frequencies the real part conductivity, /spl sigma/(/spl omega/) is frequency-independent, above a critical angular frequency gamma/ it obeys an equation form omega/)/spl prop//spl omega//sup s/. Both DC sigma//sub 0/ omega/ increases with temperature, however exponential factor s temperature-independent quantity was also observed that 10/sup 5/ Hz, tends to plateau. A nomadic polarization model quasi-one-dimensional solids used fit experimental results. Values for bulk mobility, carrier density transition rate intermolecular charge transfer were estimated.

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